The heat capacity of Sn 2 P 2 S 6 ferroelectric crystals has been measured under quasihydrostatic pressures up to 0.7 GPa. The analysis of the heat-capacity and literature data for the birefringence shows that the tricritical point of Sn 2 P 2 S 6 is in the 0.20-0.25 GPa range. Moreover, in the approximation of a linear change in the free-energy expansion coefficients, with respect to concentration and pressure, thermodynamic trajectories have been constructed for ͑Pb y Sn 1−y ͒ 2 P 2 ͑Se x S 1−x ͒ 6 solid solutions. We have thereby identified the region of the T-p-y-x diagram for ͑Pb y Sn 1−y ͒ 2 P 2 ͑Se x S 1−x ͒ 6 showing the tricritical Lifshitz point.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.