The analysis of literary data on the obtaining of cyclic carbonates based on the vegetable oils has been carried out. The influence on carbonation reaction the type of vegetable oil, the chemical composition and catalyst concentration, state of carbon dioxide, pressure and temperature have thus been considered. The carbonation process of epoxidized oils that are valuable renewable vegetable raw materials is studied insufficiently.
The
authors
have
shown
the
effective
use
of
synthesized
epoxidized
rubber
s
ee
d
oil
as
a
modifier
of
epoxy
com
pound materials. It was stated that at the content of epoxidized rubber
s
ee
d
oil of 10 weight parts for 100 weight parts of epoxy resin ED-20, hardness and
wear
have been increased by
34 and 21% correspondingly, while the frictional coefficient was being reduced
by a factor of 1.5
. Wollastonite has been synthesized on the base of rice husk and
limestone.
By means of the X-ray diffraction method, it
was proven
that the specimen of synthesized calcium silicate with the molar ratio
СаСО
3
:SiO
2
= 1.
2:1
is characterized by the structure closest to the naturally occurring wollastonite.
As a modifying additive in PVC-compositions, silicates produced by means of rice husk processing are of practical interest. Rice husk ash obtained by burning at 350°C, along with synthetic and naturally occurring wollastonite, significantly reduce plasticizer’s migration from the PVC-composition due to their porosity. This is due to the fact that the part of hydroxyl components of the plasticizer EDOS has adsorbed on the surface or retained by the silicates pores. Along with that, Miwoll 10-97 ensures a greater decrease in plasticizer’s migration than synthetic calcium silicate on the base of rice husk ash. When all the researched silicates are modified by the rice husk and naturally occurring wollastonite, heat stability of PVC-compositions grows. This is preconditioned by the alkaline origin of the surface of filling compounds that allows their possible reaction with chlorine hydride released from PVC during thermal decomposition. Synthetic and naturally occurring wollastonite enhance strain-strength properties of PVC-compositions whereas silicates on the case of rice husk reduce these parameters.
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