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Residual stress create deformations and stress in additive structures that lead to geometry deviations of created elements of 3D models and defects as pores and cracks that occur in construction process. Our work rests upon theoretical and experimental approach to the study. The main objective is to compare thermal fields with the microstructure of samples and to establish relationship between laser powder bed fusion (LPBF) modes and the structure of the samples to be created. 3D finite element method (FEM) is used for macroscopic modeling to assess the effect of thermal fields on the microstructure of Alnico alloy. Comparison of the temperature fields with the microstructure of samples made by LPBF showed that the type of scanning (both bidirectional and circular) had a strong influence on the distribution of the thermal fields and, accordingly, on the microstructure of the samples made by LPBF.