The peculiarities of sorption interactions between TMSP600 material obtained from carbonate sludge from sugar production and model sewage containing vegetable oils are investigated. It was found that in the absence of synthetic surfactants, TMSP effectively interacts with emulsions of vegetable oils and causes their rapid clarification. In the presence of sodium lauryl sulfate, efficiency is markedly reduced. The observed phenomenon is explained by the presence of a negative charge on the oil droplets, as a result of which they are repulsed from TMSP600 particles. The purification efficiency remains quite high at a synthetic surfactant concentration of <0.01 mg/dm3; therefore, TMSP600 can be considered acceptable for treating sewage contaminated with vegetable oils at a low synthetic surfactant content in the system.

Was reported literature findings of domestic and foreign articles about using of biomass components (leaves, straw, pods, seeds) and wastes of beans (Phaseolus vulgaris) and peas (Pisum sativum) pods shells processing as sorption material for pollutants (metals ions, colorants) removing from water environments. Concise literature findings about Pisum sativum and Phaseolus vulgaris plant structure, cultivation value, and chemical composition of some biomass components are described. Was revealed that composition of beans and peas pods has big amount of proteins, that can provide removing of metals ions such as (Cd(II), Co(II), Cr(III) и Cr(VI), Cu(II), Fe(III), Mo(VI), Ni(II), Pb(II), Sb(III) и Sb(V), Zn(II)) from water environments. Was showed  the possibility of sorption characteristics increase for pollutants by Phaseolus vulgaris and Pisum sativum biomass treatment with different chemical reagents. Was revealed that pollutants sorption isotherms of wastes and biomass of considered legumes are described mostly by Langmuir model than by Freundlich model. The kinetic of process mostly match to pseudo-second order model. It is shown that using of seeds and pods shells of legumes is prospectively for removing of heavy metals ions and suspended particles from water. Was proposed to use charcoal, which was gotten by peas pods carbonization for removing of heavy metals ions from water environments. Concluded, that using of legumes pods extracts is more effective for clearing water environments from heavy metals ions.

Based on data from various literature sources, information is given on the chemical composition of straw and husk of buckwheat grains. The information on buckwheat processing waste as a source for obtaining various valuable components is provided. Literature data on the use of ground buckwheat straw as a sorption material for the extraction of heavy metal ions and oil products from natural and sewage are presented. The possibility of increasing sorption characteristics by buckwheat straw treatment with various chemical reagents is shown. Determined that the husk of buckwheat grains contains cellulose and lignin most of all. Information is given on the use of the fruit shells of buckwheat grains as sorption materials for the removal of metal ions, oil and oil products from aqueous media. It was shown that to increase the sorption characteristics of these pollutants is possible by treating the sorption material with acidic chemical reagents and high-frequency low-pressure plasma. The parameters of acid treatment or plasma exposure are determined at which the highest adsorption indicators. Native straw and buckwheat husk are effective sorption materials for the removal of heavy metal ions and oil from aqueous media. It is possible to increase the sorption characteristics according to pollutants by a chemical or physical and chemical modification.

The literature data on the crushed walnut shells usageas a sorption material for metal ions, dyes and some organic compounds removal from aqueous media are summarized. Trees of the Juglans regia species are widespread in Russia; their shells are natural annually replenished material that is of industrial importance and can be used as sorption material for the extraction of many pollutants from aquatic environments. The paper gives a characteristic of the walnut shell, shows the indicators of the main substances that make up the shell (cellulose, lignin, hemicellululose), indicates the approximate specific surface area for BET and the content of functional groups. The results of studies of the adsorption of metal ions and and some dyes adsorption by walnut shellsare considered. The values of sorption indices for the studied pollutants are given. It is shown that it is possible to increase the sorption characteristics by chemical modification of the Juglans regia shell. It is determined that sorption isotherms in most cases are more fully described by the Langmuir model, and the process kinetics in all cases obeys the pseudo-second order model.

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