1-Benzoyl-3-[3-(trifluoromethyl)phenyl]thiourea

Abstract

In the title mol­ecular structure, C15H11F3N2OS, the dihedral angle between the two benzene rings is 7.1 (1)°. In the crystal structure, mol­ecules form centrosymmetric dimers via inter­molecular N—H⋯S and C—H⋯S hydrogen bonds; the dimers are stacked along [010].

Synthesis and Characterization of Copper(I) Halide Complexes with N‐(2, 6‐Diisopropylphenyl)‐N′‐benzoylthiourea: Monomeric, Dimeric, and Cage Structures

“…The crystallization of acylthiourea complexes may be relevant to the solvents, the strong hydrogen‐bonding characteristics, modification by substitution,13 or the relative concentration between reactants 14. Starting from the basic molecule of N ‐aryl‐ N ′‐benzoylthiourea, a number of derivatives have been synthesized and structurally characterized with varying aryl rings typically modified by methyl,15 carboxyl,16 phenyl,17 hydroxyl,18 trifluoromethyl,19 ferrocenoyl,10,20 and halide21 substituents. However, the isopropyl group, which has been used as a bulky group in a number of ligand systems,22 was not so common in acylthiourea derivatives 12.…”

1-(1,3-Benzothiazol-2-yl)-3-(4-chlorobenzoyl)thiourea

“…The C8-S1 and C7-O1 bond length show the expected double bond character of 1.6570 (17)Å and 1.2245 (19)Å (Saeed & Flörke 2006;Yamin & Yusof 2003). The N1-C8 is longer than N2-C8 by 0.045 Å, similar to other benzoylthiourea derivatives (Dillen et al 2006;Khawar Rauf et al 2006) which is probably due to the intramolecular hydrogen bonding interaction (Weiqun et al 2004).…”

“…For C-S and C-O bond lengths, see: Saeed & Flö rke (2006); Yamin & Yusof (2003). For the structures of other benzoylthiourea derivatives, see: Dillen et al (2006);Khawar Rauf et al (2006); Weiqun et al (2004). Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL, PARST (Nardelli, 1995) and PLATON (Spek, 2009).…”

1-(4-Nitrophenyl)-3-pivaloylthiourea

“…The bond lengths and angles are quite typical for N,N 0disubstituted thiourea compounds found in the Cambridge Structural Database (Version 5.28, Allen, 2002;Khawar Rauf et al, 2006).…”