Combination
impacts of controlling the gate-stack process conditions
and the indium contents of In–Ga–Zn–O (IGZO)
channels prepared by atomic layer deposition (ALD) were investigated
to strategically enhance the device performance including carrier
mobility for ALD IGZO thin-film transistors (TFTs). The ALD cyclic
ratios (triethyl indium/In–Ga precursor/diethyl zinc) were
varied to 0:2:2, 2:2:2, and 4:2:2 for the formation of IGZO channels,
which correspond to the In/Ga ratios of 0.3, 1.0, and 2.0. While the
device using the IGZO channel with an In/Ga ratio of 0.3 did not show
any marked difference with the variations in the type of oxidants
during the gate-stack formation processes, the carrier concentration
and relative amounts of oxygen vacancy within the IGZO channels were
found to significantly exhibit an increasing trend with increasing
In/Ga ratio, when the Al2O3 protection layer
(PL) was prepared with the oxidants incorporating a larger amount
of hydrogen-related species. Thus, the physical properties of Al2O3 PL and gate insulator (GI) were controlled by
changing the type of oxidants during the ALD processes. As a result,
the carrier mobility (9.9 cm2/V s) of the device using
an IGZO film with an In/Ga ratio of 0.3 could be enhanced to 23.5
cm2/V s by increasing the In/Ga ratio to 2.0 with the combination
of the PL formation process designed with O2-plasma. Furthermore,
the carrier mobility additionally improved to 27.6 cm2/V
s when the In/Ga ratio increased to 1.4 with simultaneously employing
the process conditions using the O3 oxidant for the formations
of PL and GI layers. The ALD IGZO TFTs fabricated with the proposed
optimum conditions also exhibited excellent bias stabilities.