To develop a low dielectric constant of LTCC substrate, we studied the effect of the sintering and crystallization behavior on the dielectric properties of a sintered body by mixing a CaO-Al 2 O 3 -SiO 2 frit and a CaO-MgO-SiO 2 frit for a low dielectric constant of LTCC substrates. In this work, the two glass frits were mixed at different proportions and sintered at 860~920°C. After sintering at 900 o C for 1h, the glass frits crystallized into diopside and anorthite. The sintered bodies exhibited dielectric properties, ɛ r =6~8.6 at 1 GHz, which is an essential condition for a substrate in microwave devices. The results suggest that the glass-ceramic can be applied to low dielectric LTCC materials in the electronics packaging industry.