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Korolev, A. V.

doi:10.1023/a:1013340620109

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“…In the case of HAM, the formation of associates with the orientation of the molecules unfavourable for chain growth is postulated (anti-precursor). The correctness of these hypotheses was strongly supported by the results of experiments 93,95,100 on the influence of small additives (one molecule per 100 molecules of the main monomer) on the rate of polymerisation comonomers possessing the same ability to undergo polymerisation via double bonds (the acryl group for HAA and the methacryl group for HAM) but containing alkyl substituents of different length. A very strong negative effect of such additives in the case of HAA was interpreted by assuming that the comonomer molecules are readily incorporated into the preassociate but simultaneously disturb the positional (or) orientational order due to the difference in the size of alkyl fragments.…”

Section: Early Stages Of Three-dimensional Radical Polymerisationmentioning

confidence: 91%

Current trends in investigations into the microheterogeneous mechanism of three-dimensional radical polymerisation

Korolev¹

2003

Russ. Chem. Rev.

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Data on the kinetics and mechanism of the three-Data on the kinetics and mechanism of the threedimensional radical polymerisation of multifunctional vinyl dimensional radical polymerisation of multifunctional vinyl monomers (oligomers) containing two (or more) double bonds monomers (oligomers) containing two (or more) double bonds are generalised and analysed. The history of this field of research is are generalised and analysed. The history of this field of research is briefly outlined. The characteristic feature of the mechanism of briefly outlined. The characteristic feature of the mechanism of three-dimensional radical polymerisation, three-dimensional radical polymerisation, i.e i.e., microheterogene-., microheterogeneity, is considered. Special attention is focused on recent advances ity, is considered. Special attention is focused on recent advances (last decade) in studies of three-dimensional radical polymer-(last decade) in studies of three-dimensional radical polymerisation associated with the development of new techniques isation associated with the development of new techniques (fiber-optic techniques, information technologies, (fiber-optic techniques, information technologies, etc. etc.). Consid-). Consideration is given to methodological aspects of kinetic experiments eration is given to methodological aspects of kinetic experiments in highly cross-linked reaction media in which three-dimensional in highly cross-linked reaction media in which three-dimensional radical polymerisation proceeds. The bibliography includes 223 radical polymerisation proceeds. The bibliography includes 223 references references. .

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Section: Early Stages Of Three-dimensional Radical Polymerisationmentioning

confidence: 91%

Current trends in investigations into the microheterogeneous mechanism of three-dimensional radical polymerisation

Korolev¹

2003

Russ. Chem. Rev.

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show abstract

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Cited by 1 publication

References 2 publications

Current trends in investigations into the microheterogeneous mechanism of three-dimensional radical polymerisation

Current trends in investigations into the microheterogeneous mechanism of three-dimensional radical polymerisation

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