Recently, β-Ga 2 O 3 has attracted extensive attention because of its ultrawide bandgap (%4.8 eV), [1,2] high theoretical breakdown electric field (E br ) (8 MV cm À1 ), [3,4] and higher Baliga figure of merit (BFOM) compared with GaN and SiC. The highly mature bulk growth and thin film deposition techniques [5][6][7] make both homo- [8][9][10] and heteroepitaxial [11,12] growth of Ga 2 O 3 thin films with controllable doping possible, [13][14][15][16] which is important for practical applications such as power switches, [17,18] high-efficiency devices, [19] and deep-UV photodetectors. [20,21] To develop and optimize modern electronic and optoelectronic devices with great flexibility, energy band engineering is necessary for designing and preparing barrier layers, which show better carrier confinement with larger band offsets in device structures. [22] It has been demonstrated that the bandgap of β-(Al x Ga 1Àx ) 2 O 3 depends on the Al composition (x), and increases with it. [23] Many works in the literature report the growth of β-(Al x Ga 1Àx ) 2 O 3 thin films using molecular beam epitaxy (MBE), [24][25][26] metal organic chemical vapor deposition (MOCVD), [27] pulsed laser deposition (PLD), [28] sputtering [29] and solution combustion synthesis, [30] etc., and studies on the Al incorporation effect on the surface morphology and crystalline quality, which are summarized in Table 1. β-(Al x Ga 1Àx ) 2 O 3 epitaxial film by MOCVD and MBE is mainly used for highpower electronic applications. For instance, by constructing a β-(Al x Ga 1Àx ) 2 O 3 /β-Ga 2 O 3 heterojunction with a Si delta-doped layer in β-(Al x Ga 1-x ) 2 O 3 to prepare a modulated doped field effect