Silicon dioxide films deposited by plasmaenhanced chemical vapor deposition (PECVD) are useful as interlayer dielectric for metal-insulator structures such as MOS integrated circuits and multichip modules. The PECVD of Si02 in a SiH4/N20 gas mixture yields films with excellent physical properties. However, due to the complex nature of particle dynamics within the plasma, it is difficult to determine the exact nature of the relationship between film properties and controllable deposition conditions. Previous modeling techniques such as first principles or statistical response surface methods are limited in either efficiency or accuracy. In this study, PECVD modeling using neural networks has been introduced. Neural networks have been shown to exhibit superior performance in both accuracy and prediction capability compared to statistical models.The PECVD of Si02 was characterized via a 251 fractional factorial experiment, and data from this experiment was used to train neural networks using feed-forward error back-propagation (FFEBP) algorithm. From these neural process models, the effect of deposition condition on film properties has been studied, and sensitivity analysis has been performed to determine the impact of individual parameters. The deposition experiments were carried out in a Plasma Therm 700 series PECVD system. The models obtained will ultimately be used for several other manufacturing applications, including recipe generation and optimization, and process control.
ThJTRODUCTIONChemical vapor deposition (CVD) is an important processing technique in the manufacture of integrated circuits. The CVD process consists of the formation of a non-volatile solid film on a substrate by the reaction of vapor phase chemicals (reactants) that contain the required constituents. While atmospheric CVD (APCVD) and low pressure C\'D (LPCVD) are currently the dominant methods of employing CVD, some processes require a lower thermal budget than these two techniques allow. As opposed to thermally grown Si02, CVD Si02 is often used to maintain shallow diffusions or to prevent changes in profiles. Both APCVD and LPCVD Si02 yield films with good electrical properties, and the deposition processes are relatively straightforward. However, when these layers are deposited on silicon wafers, both materials are in tension. This not only reduces mechanical strength, but also limits the film thickness.Plasma-deposited oxide, on the other hand, is usually in compression, allowing film thickness up to 5 im to be obtained without cracking. Rather than relying solely on thermal energy to initiate and sustain chemical reactions, plasmaenhanced CVD (PECVD) uses a radio frequency (RF) induced glow discharge to transfer energy into the reactant gases, allowing the substrate to remain at a lower temperature than in APCVD or LPCVD. In the presence of the plasma, the reactant gases are transformed to various active species (such as neutral radicals and ions) due to collisions with energetic electrons. The highly reactive nature of these specie...