We present results from ALMA 1.2 mm continuum observations of a sample of 27 star-forming galaxies at z = 2.1 − 2.5 from the MOSFIRE Deep Evolution Field (MOSDEF) survey. These galaxies have gas-phase metallicity and star-formation rate measurements from Hβ, [Oiii], Hα, and [Nii]. Using stacks of Spitzer, Herschel, and ALMA photometry (rest-frame ∼ 8 − 400 µm), we examine the IR SED of high-redshift subsolar metallicity (∼ 0.5 Z ) LIRGs. We find that the data agree well with an average SED template of higher luminosity local low-metallicity dwarf galaxies (reduced χ 2 of 1.8). When compared with the commonly used templates for solar-metallicity local galaxies or highredshift LIRGs and ULIRGs, even in the most favorable case (with reduced χ 2 of 2.8), the templates are rejected at > 98% confidence level. The broader and hotter IR SED of both the local dwarfs and high-redshift subsolar metallicity galaxies may result from different grain properties, a clumpy dust geometry, or a harder/more intense ionizing radiation field that heats the dust to higher temperatures. The obscured SFR indicated by the FIR emission of the subsolar metallicity galaxies is only ∼ 60% of the total SFR, which is considerably lower than that of the local LIRGs with ∼ 96 − 97% obscured fractions. Due to the evolving IR SED shape, the local LIRG templates fit to mid-IR data can overestimate the Rayleigh-Jeans tail measurements at z ∼ 2 by a factor of 2 − 20, and these templates underestimate IR luminosities if fit to the observed ALMA fluxes by > 0.4 dex. At a given stellar mass or metallicity, dust masses at z ∼ 2.3 are an order of magnitude higher than those at z ∼ 0. Given the predicted molecular gas mass fractions, the observed z ∼ 2.3 dust-to-stellar mass ratios suggest lower dust-to-molecular gas masses than in local galaxies at the same metallicity. CO observations are necessary to better constrain the molecular gas content of sub-solar metallicity galaxies at z > 1.