We performed high-resolution angle-resolved photoemission spectroscopy on Nd1.87Ce0.13CuO4, which is located at the boundary of the antiferromagnetic (AF) and the superconducting phase. We observed that the quasiparticle (QP) effective mass around (π, 0) is strongly enhanced due to the opening of the AF gap. The QP mass and the AF gap are found to be anisotropic, with the largest value near the intersecting point of the Fermi surface and the AF zone boundary. In addition, we observed that the QP peak disappears around the Néel temperature (TN ) while the AF pseudogap is gradually filled up at much higher temperatures, possibly due to the short-range AF correlation.Since the discovery of cuprate high-temperature superconductors (HTSCs), intensive experimental and theoretical studies have been performed to elucidate the origin and mechanism of the anomalously high superconducting (SC) transition temperature. It is now widely accepted that electrons or holes doped into the parent Mott insulator interact antiferromagnetically with each other on the quasi-two dimensional CuO 2 plane. Although it has been suggested that the antiferromagnetic (AF) interaction plays an essential role for pairing of electrons (holes) in the SC state, it is still unclear how the antiferromagnetism interplays with the superconductivity at the microscopic level. This problem is a central issue not only in HTSCs but also in other exotic superconductors such as heavy-fermion and organic-salt superconductors. In the phase diagram of electron-doped cuprates, the AF and SC phases are adjacent to each other or somewhat overlap at the boundary, in contrast to the hole-doped case where the two phases are well separated [1]. The proximity or overlapping between the AF and SC phases in the electron-doped cuprates yields a good opportunity for studying the interplay between the AF interaction and the superconductivity [2,3,4,5]. In fact, a recent elastic neutron-scattering experiment reported a competitive nature between the AF long-range order and the superconductivity [2]. On the other hand, an inelastic neutron scattering experiment observed coexistence of the gapped commensurate spin fluctuation and the superconductivity [3]. In contrast to these intensive studies on the "qresolved" spin dynamics by neutron scattering, a limited number of photoemission studies on the "k-resolved" electronic structure have been reported for electron-doped cuprates [6,7]. The k-dependence of the AF correlation effect on the electronic structure is essential to understand the interplay between the antiferromagnetism and the superconductivity.In this Letter, we report high-resolution angle-resolved photoemission spectroscopy (ARPES) on electron-doped cuprate Nd 1.87 Ce 0.13 CuO 4 (NCCO, x = 0.13) located at the phase boundary between the AF and SC phases. We found the mass-renormalized quasiparticle (QP) state near (π, 0), which gradually evolves into the high-energy gap [6] around the hot spot. The observed continuous evolution of the electronic structure near the Fe...