2015
DOI: 10.1016/j.electacta.2015.01.214
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A high performance cobalt sulfide counter electrode for dye-sensitized solar cells

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Cited by 93 publications
(33 citation statements)
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“…2c are also provided to reconfirm the catalytic activity and charge-transfer ability. Two crucial parameters including J0 (exchange current density obtained from the tangent for anodic or cathodic branches, J0 = RT/nFRct) [22] and Jlim (limiting diffusion current density from the intersection of the cathodic branch with Y-axis, Jlim = 2nFCDn/l) [23] can be determined, as listed in Table 1. The extracted Rct and Dn follow the same order to that from EIS and CV characterizations, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…2c are also provided to reconfirm the catalytic activity and charge-transfer ability. Two crucial parameters including J0 (exchange current density obtained from the tangent for anodic or cathodic branches, J0 = RT/nFRct) [22] and Jlim (limiting diffusion current density from the intersection of the cathodic branch with Y-axis, Jlim = 2nFCDn/l) [23] can be determined, as listed in Table 1. The extracted Rct and Dn follow the same order to that from EIS and CV characterizations, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Recently, inorganic metal compounds based Pt-free catalysts for use in DSSCs developed rapidly, such as carbides [17][18][19][20][21][22][23], nitrides [24][25][26], oxides [27][28][29], sulfides [30][31][32][33][34][35][36][37] as well as selenides [38][39]. For example, Yang et al reported low cost Sn x S CE for DSSCs and demonstrated comparable power conversion efficiency to Pt [40].…”
Section: Introductionmentioning
confidence: 99%
“…However, the high cost, abundance deficiency, and corrosion in triiodide solution make Pt unsuitable for commercial purpose of DSSCs [3]. Therefore, many functional materials have been investigated for Pt-free counter electrodes, such as carbon materials [4], conducting polymers [5][6][7][8][9][10][11][12][13], some metal-based inorganic compounds [14][15][16][17], and composite materials [18][19][20]. As a substituted polythiophene, poly(3,4-ethylenedioxythiophene) (PEDOT) has been widely studied due to its high conductivity, electrochemical stability, catalytic ability, and easy fabrication in large scale.…”
Section: Introductionmentioning
confidence: 99%