A high strength pH responsive supramolecular copolymer hydrogel

Wang, Qing; Zhang, Yinyu; Dai, XiYang; Shi, Xiaohuan; Liu, Wenguang

doi:10.1007/s11431-016-0698-0

Cited by 21 publications

(10 citation statements)

References 32 publications

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“…Recently, we copolymerized N ‐acryloyl glycinamide (NAGA) and VDT without any chemical crosslinking agent. The obtained supramolecular polymer hydrogels exhibited high mechanical performance and pH response …”

Section: Pvdt‐based High‐strength Hydrogelsmentioning

confidence: 99%

Poly(vinyl diaminotriazine): From Molecular Recognition to High‐Strength Hydrogels

Liu

2018

Macromol. Rapid Commun.

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Poly(2-vinyl-4,6-diamino-1,3,5-triazine), (PVDT) with diaminotriazine residues is found to form not only intramolecular hydrogen bonds, but also three robust, complementary hydrogen bonds with nucleobases such as thymine and uracil. Taking advantage of the three complementary hydrogen bonds, molecular recognition of a nucleic acid base has been investigated in previous work. Over the past few years, the use of PVDT has been extended to the construction of gene delivery vectors and nonswellable, high-strength hydrogels by copolymerization with a hydrophilic monomer and/or crosslinker. In particular, many fascinating properties, such as excellent mechanical properties, stimuli responsiveness, the shape memory effect, and biodegradability, have emerged in PVDT-based hydrogels. In this article, the molecular recognition and self-assembly of diaminotriazine are introduced first, and then a particular focus is placed on the development of PVDT-based high performance hydrogels, especially their biorelated applications.

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Section: Pvdt‐based High‐strength Hydrogelsmentioning

confidence: 99%

Poly(vinyl diaminotriazine): From Molecular Recognition to High‐Strength Hydrogels

Liu

2018

Macromol. Rapid Commun.

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“…We envisaged that the introduction of diaminotriazine residues into graphene-based hydrogels would open up new alternative routes to hydrophobic drug delivery. The non-covalent nature of DAT-based hydrogels endows hydrophobicity as well as stimuli-responsiveness, 22,23 both of which are requisites for these applications. On the other hand, we previously observed that graphene interacts favourably with DAT thin films through π-π and NH 2 -graphene interactions and combination of the two aforementioned elements may make graphene-diaminotriazine (G-DAT) hybrid hydrogels useful platforms for the controlled release of hydrophobic drugs.…”

Section: Introductionmentioning

confidence: 99%

Stimuli-responsive graphene-based hydrogel driven by disruption of triazine hydrophobic interactions

et al. 2020

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“…The numerical results reveal that the stretch ratio has a significant effect on the changes of transition temperatures for the SMP. Furthermore, as the transition temperature is decreased to a certain value, the stored mechanical energy in the polymer is released, and accordingly the SME is triggered [43][44][45][46][47]. As an example, the g T is increased with a value of 10K when the frequency is increased from 0.001Hz to 10Hz.…”

Section: Modelling Of Thermo-/chemo-responsive Multi-smementioning

confidence: 99%

A thermomechanical model of multi-shape memory effect for amorphous polymer with tunable segment compositions

Wang

Shi

et al. 2019

Composites Part B: Engineering

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Multi-shape memory effect (multi-SME) in amorphous polymers has attracted great attention due to their complex thermal transitions and multi-step recovery behavior. Many experimental studies have been reported for synthesis, characterization, testing and demonstration of the multi-SME. However, theoretical approaches have seldom been applied although they are critically needed to understand the principles and predict the behavior of the multi-SME in various amorphous polymers. In this study, a new thermomechanical model was proposed to describe the thermo-/chemo-responsive multi-SME of amorphous polymers with tunable segment compositions. Based on the Weibull statistical model, a new constitutive framework was established to describe temperature-, stretch ratio-and strain-dependent behaviors of thermo-/chemo-responsive multi-SME. Finally, this newly proposed model was applied to quantitatively identify the crucial factors for the thermo-/chemo-responsive shape recovery behaviors, which have been verified by the reported experimental data.

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A high strength pH responsive supramolecular copolymer hydrogel

Cited by 21 publications

References 32 publications

Poly(vinyl diaminotriazine): From Molecular Recognition to High‐Strength Hydrogels

Poly(vinyl diaminotriazine): From Molecular Recognition to High‐Strength Hydrogels

Stimuli-responsive graphene-based hydrogel driven by disruption of triazine hydrophobic interactions

A thermomechanical model of multi-shape memory effect for amorphous polymer with tunable segment compositions

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