One-dimensional
semiconductor nanostructures, such as nanowires
(NWs), have attracted tremendous attention due to their unique properties
and potential applications in nanoelectronics, nano-optoelectronics,
and sensors. One of the challenges toward their integration into practical
devices is their large-scale controlled assembly. Here, we report
the guided growth of horizontal CdSe nanowires on five different planes
of sapphire. The growth direction and crystallographic orientation
are controlled by the epitaxial relationship with the substrate as
well as by a graphoepitaxial effect of surface nanosteps and grooves.
CdSe is a promising direct-bandgap II–VI semiconductor active
in the visible range, with potential applications in optoelectronics.
The guided CdSe nanowires were found to have a wurtzite single-crystal
structure. Field-effect transistors and photodetectors were fabricated
to examine the nanowire electronic and optoelectronic properties,
respectively. The latter exhibited the fastest rise and fall times
ever reported for CdSe nanostructures as well as a relatively high
gain, both features being essential for optoelectronic applications.