Thermocouples are increasingly used in industry and research. For many industrial heating processes, particularly those carried out at high temperatures, a thermocouple is the most convenient and simple instrument for temperature measurement. In some instances, it is the only feasible method. The aim of this study is to select and recommend the best thermocouples from both base and noble metals to users in industrial and scientific institutions. Different types of thermocouples and calibration methods are described. From this work, the Nicrosil-Nisil thermocouple has been proposed as the best base metal thermocouple and the Au/Pt thermocouple is the most recommended as a substandard up to 1,000 • C.