The complexity and age of industrial plants have prompted a rapid increase in equipment maintenance and replacement activities in recent years. Consequently, plant owners are challenged to reduce the process and review time of equipment purchase order (PO) documents. Currently, traditional keyword-based document search technology generates unintentional errors and omissions, which results in inaccurate search results when processing PO documents of equipment suppliers. In this study, a purchase order knowledge retrieval model (POKREM) was designed to apply knowledge graph (KG) technology to PO documents of steel plant equipment. Four data domains were defined and developed in the POKREM: (1) factory hierarchy, (2) document hierarchy, (3) equipment classification hierarchy, and (4) PO data. The information for each domain was created in a graph database through three subprocesses: (a) defined in a hierarchical structure, (b) classified into nodes and relationships, and (c) written in triples. Ten comma-separated value (CSV) files were created and imported into the graph database for data preprocessing to create multiple nodes. Finally, rule-based reasoning technology was applied to enhance the model’s contextual search performance. The POKREM was developed and implemented by converting the Neo4j open-source graph DB into a cloud platform on the web. The accuracy, precision, recall, and F1 score of the POKREM were 99.7%, 91.7%, 100%, and 95.7%, respectively. A validation study showed that the POKREM could retrieve accurate answers to fact-related queries in most cases; some incorrect answers were retrieved for reasoning-related queries. An expert survey of PO practitioners indicated that the PO document review time with the POKREM was reduced by approximately 40% compared with that of the previous manual process. The proposed model can contribute to the work efficiency of engineers by improving document search time and accuracy; moreover, it may be expandable to other plant engineering documents, such as contracts and drawings.