Using a particle-in-cell simulation, the dispersion and growth rate of the ion-acoustic mode are investigated for a plasma containing two ion and two electron components. The electron velocities are modelled by a combination of two kappa distributions, as found in Saturn's magnetosphere. The ion components consist of adiabatic ions and an ultra-low density ion beam to drive a very weak instability, thereby ensuring observable waves. The ion-acoustic mode is explored for a range of parameter values such as κ, temperature ratio, and density ratio of the two electron components. The phase speed, frequency range, and growth rate of the mode are investigated. Simulations of double-kappa two-temperature plasmas typical of the three regions of Saturn's magnetosphere are also presented and analysed.