A study of mechanism of nickel interferences in hydride generation atomic absorption spectrometric determination of arsenic and antimony

Henden, Emür; İşlek, Yasemin; Kavas, Miray; Aksuner, Nur; Yayayürük, Onur; Çiftçi, Tülin Deniz; İlktaç, Raif

doi:10.1016/j.sab.2011.10.001

Cited by 24 publications

(12 citation statements)

References 21 publications

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“…Cd, Co, Cu, Fe, Ni, Pb, Zn) and hydrideforming elements (e.g. As, Ge, Se, Sn, Te) can inhibit the formation of stibine (SbH 3 ) and/or lead to matrix effect during analysis (Yu et al 1983;Kumar and Riyazuddin 2010;Henden et al 2011). …”

Section: 3b Sb Preconcentration and Purification Proceduresmentioning

confidence: 99%

Antimony isotopic composition in river waters affected by ancient mining activity

Resongles

Freydier

Casiot

et al. 2015

Talanta

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In this study, antimony (Sb) isotopic composition was determined in natural water samples collected along two hydrosystems impacted by historical mining activities: the upper Orb River and the Gardon River watershed (SE, France). Antimony isotope ratio was measured by HG-MC-ICP-MS (Hydride Generation Multi-Collector Inductively Coupled Plasma Mass Spectrometer) after a preconcentration and purification step using a new thiol-cellulose powder (TCP) procedure. The external reproducibility obtained for δ(123)Sb measurements of our in-house Sb isotopic standard solution and a certified reference freshwater was 0.06‰ (2σ). Significant isotopic variations were evident in surface waters from the upper Orb River (-0.06‰≤δ(123)Sb≤+0.11‰) and from the Gardon River watershed (+0.27‰≤δ(123)Sb≤+0.83‰). In particular, streams that drained different former mining sites exploited for Sb or Pb-Zn exhibited contrasted Sb isotopic signature, that may be related to various biogeochemical processes occurring during Sb transfer from rocks, mine wastes and sediments to the water compartment. Nevertheless, Sb isotopic composition appeared to be stable along the Gardon River, which might be attributed to the conservative transport of Sb at distance from mine-impacted streams, due to the relative mobile behavior of Sb(V) in natural oxic waters. This study suggests that Sb isotopic composition could be a useful tool to track pollution sources and/or biogeochemical processes in hydrologic systems.

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Section: 3b Sb Preconcentration and Purification Proceduresmentioning

confidence: 99%

Antimony isotopic composition in river waters affected by ancient mining activity

Resongles

Freydier

Casiot

et al. 2015

Talanta

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“…Previous work has reported that HG-AFS is susceptible to interferences from some transition and noble metal ions, such as Cu 2+ , Zn 2+ or Fe 3+ [32] as these metal ions can be reduced by KBH 4 to their colloidal metal forms, which can decompose the hydrides of Cd and As [33]. In this work, an excellent anti-interference capability was demonstrated.…”

Section: Interferencementioning

confidence: 64%

Simultaneous determination of arsenic and cadmium by hydride generation atomic fluorescence spectrometry using magnetic zero-valent iron nanoparticles for separation and pre-concentration

Luo

Wang

Dai

et al. 2017

Microchemical Journal

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“…The purpose of this study is to develop a preconcentration system for the determination of Hg 2+ and CH3Hg + in water. For this purpose, adsorbent Ni/NixB nanoparticles were synthesized in the same manner as in a recent study by Henden et al 30 In this study, the selectivity of these nanoparticles towards inorganic Hg 2+ and organic CH3Hg + was investigated for the first time. The efficiency of the adsorbent was studied as a preconcentration agent and was then tested by spike recovery tests.…”

Section: Introductionmentioning

confidence: 99%

Use of Ni/NixB Nanoparticles as a Novel Adsorbent for the Preconcentration of Mercury Species prior to Cold Vapor-Atomic Fluorescence Spectrometric Determination

Yayayürük

Henden

2016

ANAL. SCI.

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A selective matrix separation/enrichment method, utilizing a simple batch procedure with nickel/nickel boride (Ni/NixB) nanoparticles was proposed for the determination of inorganic mercury(II), Hg(2+) and methyl mercury(I), CH3Hg(+) in waters prior to cold vapor-atomic fluorescence spectrometry (CV-AFS). The Ni/NixB nanoparticles, were synthesized by the chemical reduction of Ni(II) to Ni/NixB. The novel adsorbent was selective to Hg(2+) and CH3Hg(+) species between pH values of 4 - 10. Both of the mercury species were recovered from the adsorbent using 1.0 mol L(-1) hot HNO3 with high efficiency. It was observed that the adsorbent selectively removed Hg(2+) and CH3Hg(+) from the bulk solution in the presence of several competitor ions (As(3+), Sb(3+), Pb(2+), Zn(2+), Cu(2+), Cd(2+) and Fe(3+)) with ≥96% adsorption. The limit of detection (3σ above blank) was found to be 1.8 ng L(-1) with a preconcentration factor of 20. The validation of the method was tested through spike recovery experiments with several water samples (tap and seawater) at μg L(-1) concentration levels, and all recovery values were found to vary between 95 and 105%.

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A study of mechanism of nickel interferences in hydride generation atomic absorption spectrometric determination of arsenic and antimony

Cited by 24 publications

References 21 publications

Antimony isotopic composition in river waters affected by ancient mining activity

Antimony isotopic composition in river waters affected by ancient mining activity

Simultaneous determination of arsenic and cadmium by hydride generation atomic fluorescence spectrometry using magnetic zero-valent iron nanoparticles for separation and pre-concentration

Use of Ni/NixB Nanoparticles as a Novel Adsorbent for the Preconcentration of Mercury Species prior to Cold Vapor-Atomic Fluorescence Spectrometric Determination

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