A Study of the Configuration of the Nickel Salt of Formyl Camphor

French, Helen S.; Corbett, G.E.

doi:10.1021/ja01868a092

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1943

2013

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Cited by 3 publications

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“…The inactive form of this compound, however, has been shown by D. P. Mellor (119) to be diamagnetic; hence the Ni(II) atom is square coordinated. In contrast with this conclusion, H. S. French and G. Corbett (65) have concluded that the Ni(II) atom is tetrahedrally coordinated in bis(d-formylcamphor) nickel(II), which compound is paramagnetic. Clearly there is some anomaly here if the mag- netic moment can be accepted as a reliable criterion of stereochemistry.…”

Section: A Ionic Latticesmentioning

confidence: 90%

The Stereochemistry and Valence States of Nickel.

Nyholm¹

1953

Chem. Rev.

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Section: A Ionic Latticesmentioning

confidence: 90%

The Stereochemistry and Valence States of Nickel.

Nyholm¹

1953

Chem. Rev.

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“…There is first of all Jensen's observation (75) that paramagnetic [Ni((C2H6)3P)2(N03)2] has a large electric dipole moment which presumably arises from a tetrahedral arrangement of the attached groups rather than from the less stable cfs-planar arrangement. Secondly, there are the data of French and Corbett (51) on the rotatory dispersion and absorption of paramagnetic nickel formylcamphor. The argument used here was that since nickel formylcamphor showed the Cotton effect in a band (maximum at 3172 A.…”

Section: Complexesmentioning

confidence: 99%