2008
DOI: 10.1016/j.tsf.2007.10.087
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A thin chromium film formation monitoring method: Monitoring of the early stages

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Cited by 7 publications
(5 citation statements)
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“…The 100-Nitrate XPS spectrum has four peaks from deconvolution analysis. The small peaks at approximately binding energy at 576.3 eV and 585.3 eV are due to Cr 3+ species; whereas, the other two peaks are from Cr 6+ close to 579.3 eV and 588.3 eV [34,[53][54][55]. The 100-Nitrate, 50-Nitrate and 25-Nitrate indicate co-existence of Cr 3+ and Cr 6+ together.…”
Section: X-ray Photoelectron Spectroscopymentioning
confidence: 91%
“…The 100-Nitrate XPS spectrum has four peaks from deconvolution analysis. The small peaks at approximately binding energy at 576.3 eV and 585.3 eV are due to Cr 3+ species; whereas, the other two peaks are from Cr 6+ close to 579.3 eV and 588.3 eV [34,[53][54][55]. The 100-Nitrate, 50-Nitrate and 25-Nitrate indicate co-existence of Cr 3+ and Cr 6+ together.…”
Section: X-ray Photoelectron Spectroscopymentioning
confidence: 91%
“…O 2 plasma induced oxidation [8])/Cr/Cr x O y (i.e. Cr x O y formation mechanism as observed in [9]) multilayered composite-substrate system. Specifically, the O 2 plasma process was employed as it is much more effective compared to thermal process and uses a different oxidation mechanism, because of the atomic oxygen present in the plasma.…”
Section: Thin Film Depositionmentioning
confidence: 93%
“…In conclusion, catalytic activity can be excluded. So far, we can only speculate about the real [28][29][30] HF does not attack Cr 2 O 3 but rather passivates the surface. [31] Thus, a similar interface effect as with the Ti adhesion layer is excluded at the moment.…”
Section: (4 Of 7)mentioning
confidence: 99%
“…Chromium is oxygen active forming about 1 nm oxide under ambient conditions and an initial Cr 2 O 3 layer during initial physical vapor deposition phase. [ 28–30 ] HF does not attack Cr 2 O 3 but rather passivates the surface. [ 31 ] Thus, a similar interface effect as with the Ti adhesion layer is excluded at the moment.…”
Section: Figurementioning
confidence: 99%