Acid-base properties of glass surfaces

Fowkes, Frederick M.; Dwight, D. W.; Cole, David A.; Huang, Tzu-Ling

doi:10.1016/0022-3093(90)90190-w

Cited by 95 publications

(50 citation statements)

References 7 publications

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“…The contribution of the dispersive forces to the work of adhesion can be quantified by means of the Fowkes approach [34,61]:…”

Section: Work Of Adhesion and Interfacial Tensionmentioning

confidence: 99%

“…Intermolecular forces that are operating between molecular segments of polymers and at particulate interfaces are frequently cited in the literature [3,[26][27][28][29][30][31][32][33][34][35] as being responsible for the properties of the system as a whole. In the particular case of polymer nanocomposites, e.g.…”

Section: Introductionmentioning

confidence: 99%

“…This is because such intermolecular forces are known to dominate over dispersion intermolecular forces and dipole-dipole intermolecular forces [2,5,[12][13][14]16,31,34,35,[40][41][42][43][44]. This is clear in the definition of specific interactions, given by Huyskens et al [16], ''specific interactions are short-range, site-bounded cohesion forces that considerably weaken a given chemical bond of one of the partners''.…”

Section: Introductionmentioning

confidence: 99%

“…The approach of Fowkes is based on his definition of work of adhesion between two apolar species [34]. Thus [24],…”

Section: Dispersive Component Of the Surface Free Energy Of Solid Surmentioning

confidence: 99%

“…The solubility parameter was originally intended to be applied to substances whose cohesion arises from dispersion forces [34]. Moreover, this parameter seems to be of limited use with polymers that generally decompose before vaporisation enthalpies can be determined [11].…”

Section: The Solubility Parametermentioning

confidence: 99%

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Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography

Santos

Guthrie

2005

Materials Science and Engineering: R: Reports

107

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The properties of a polymeric system are a consequence of the interactions that occur between the various components of these complex systems. These components may vary significantly in terms of chemical nature (e.g. organic/inorganic), physical properties (e.g. particle size, surface area, molecular weight), structural characteristics and proportion in the formulations composition. This review paper addresses the major approaches in use regarding the analysis of the interactions that occur between the polymeric system components and the use of such approaches in the interpretation of the chemical, physical and thermodynamic properties of these systems. Special attention is given to the technique of inverse gas chromatography.A case study is presented, where use was made of inverse gas chromatography to characterize thermodynamically the surface of the major components of pigmented PC/PBT blends. The concept of Lewis acidity/basicity was used in the interpretation of the intermolecular interactions nature and potential in these blends, as encountered in phase separation and phase preferences phenomena and as expressed in the morphology, the physical and the mechanical properties of these commercially important composites. #

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“…The contribution of the dispersive forces to the work of adhesion can be quantified by means of the Fowkes approach [34,61]:…”

Section: Work Of Adhesion and Interfacial Tensionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

“…The approach of Fowkes is based on his definition of work of adhesion between two apolar species [34]. Thus [24],…”

Section: Dispersive Component Of the Surface Free Energy Of Solid Surmentioning

confidence: 99%

Section: The Solubility Parametermentioning

confidence: 99%

See 3 more Smart Citations

Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography

Santos

Guthrie

2005

Materials Science and Engineering: R: Reports

107

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Study of the Silicon/?-APS/Pyralin Assembly Interfaces by X-ray Photoelectron Spectroscopy

George

Viel

Bureau

et al. 1996

Surf. Interface Anal.

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Polyimides have been extensively studied in view of their wide industrial applications. Adhesion to a substrate is essential for normal operation of devices. This problem is often solved by the use of an adhesion promoter on the surface of interest. A surface‐sensitive technique such as XPS has proved to be a powerful analytical tool for the analysis of the polymer/substrate interface. In the present paper, the interfaces of the SiO2/γ‐aminopropyltriethoxysilane (γ‐APS)/Pyralin system have been investigated at a precured stage. A detailed analysis of the molecular structures formed at the interface is carried out using XPS spectroscopy. An attribution of the various peak components is made with the help of accurate calculations of presumed core‐electron binding energies using a recent procedure based on the Density Functional Theory. Two acid–base mechanisms are described. The first one occurs between the ammonium end of the γ‐APS molecule and the silicon surface hydroxyl (NH3U+SiO‐), whereas the second one is formed between the ammonium end of the γ‐APS and the polymer carboxylic function (NH3U+COO‐). The results at the first interface are in contradiction with the expected stable oxygen‐bridged bond (siloxane), thus the rearrangement of the γ‐APS molecule upon heating, as suggested by Linde in a dynamic ‘Flip model,’ has been studied.

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Use of aminosilane coupling agent in the synthesis of conducting, hybrid polypyrrole-silica gel particles

Perruchot

Chehimi

Delamar

et al. 1998

Surf. Interface Anal.

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Acid-base properties of glass surfaces

Cited by 95 publications

References 7 publications

Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography

Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography

Study of the Silicon/?-APS/Pyralin Assembly Interfaces by X-ray Photoelectron Spectroscopy

Use of aminosilane coupling agent in the synthesis of conducting, hybrid polypyrrole-silica gel particles

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