Addition diastéréosélective d'organo-cuprates à des imides chirales insaturées

Pourcelot, G.; Aubouet, J.; Caspar, A.; Cresson, P.

doi:10.1016/0022-328x(87)80264-4

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Conjugate Additions2

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2013

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Cited by 15 publications

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“…Conjugate additions of organocuprates to R,βunsaturated N-acyloxazolidinones 116 proceed with good diastereoselectivity and allow access to β-branched carboxylic acids (Scheme 116), 26 or β-substituted GABA analogs. 519 In addition to copper-based reagents, 26,436,520 aluminum can also be used to deliver a nucleophile in a 1,4-manner. 475,521 The carbon-carbon bond formation was further extended to prepare allylated products by the conjugate addition of allyltrimethylsilane to R,β-unsaturated N-acyloxazolidinone 116 (Scheme 117).…”

Section: Conjugate Additionsmentioning

confidence: 99%