Adducts of InCl3 with Lewis bases: Crystal and molecular structure of [(InCl3)2(DME)3]

The spray-ILGAR® (ion layer gas reaction) method for the deposition of thin semiconductor layers: Process and applications for thin film solar cells

“…The experiment revealed the increased volatility of InCl 3 in the presence of ethanol. From the literature, it is known that indium forms complexes with three molecules of a Lewis base [21,22], e.g. In(C 2 H 5 OH) 3 (3)) cannot be ruled out.…”

Non-aqueous solvent extraction of indium from an ethylene glycol feed solution by the ionic liquid Cyphos IL 101: speciation study and continuous counter-current process in mixer–settlers

“…As a consequence, as more and more indium(III) is coordinated to EG, the fraction of EG present in trans Based on elemental, thermogravimetric, infra-red, mass spectrometry and single crystal X-ray analysis, it was proposed that the (InCl 3 ) 2 (DME) 3 complex composed out of two centrosymmetrically related lnCl 3 -$DME$0.5DME units, where the indium(III) is coordinated to three chlorine atoms, two oxygen atoms of one chelating DME unit and one oxygen atom of the bridging DME ligand in a facoctahedral arrangement, resulting in a six-coordinate complex. 60 Complexes with bridging ligands are common in crystal structures. Metal complexes were EG serves as a bridging complex are reported for sodium and copper.…”

(μ-1,2-Dimethoxyethane-κ2O:O′)bis[(1,2-dimethoxyethane-κ2O,O′)tris(1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olato-κ2O,O′)cerium(III)]

“…[Symmetry code: (i) Àx + 1, Ày + 1, Àz + 1.] Becker et al, 2004)], transition metals [Mo (PAHNIW;Parsons et al, 2004) and Pd (MOBQEZ;Lohner et al, 2002)] and main group metals [Al (SAMLAT;Saied et al, 1998) and In (ZADCOW; Carta et al, 1995)]. Structures of this nature incorporating lanthanide ions are limited to six reported examples: [Ln(NCS) 3 (dme) 2 (-dme) 0.5 ] 2 [Ln = Eu (CUYLIS), Dy (CUYLOY) and Er (CUYLUE); Bakker et al, 2010], [Nd 2 (OCH-i-Pr 2 ) 6 (-dme)] n (HANJEL; Barnhart et al, 1993), [YbI 2 (dme) 2 ] 2 (-dme) (HOXYAU;Grö b et al, 2000) and [Nd(3,5-di-t-butylpyrazolato)(-dme)] n (TUMJIU; Cosgriff et al, 1996).…”