An electrochemical study of the photolysis of adsorbed flavins

Electrocatalytic properties of NDGA and NDGA/FAD hybrid film modified electrodes for NADH/NAD+ redox reaction

“…FAD has an isoalloxazine ring as its redoxactive component. The absorption of FAD has been studied on Hg electrodes [9], on the surface of titanium electrodes [10], and its electrochemical properties have also been determined [11]. Scheme 1.…”

The electrochemical self-assembly of the FAD modified zinc oxide films and their electrocatalytic properties

“…FAD has an isoalloxazine ring as a redox-active component. The absorption 0022 of FAD has been studied on Hg electrode [32], on the surface of titanium electrodes [33], and its electrochemical properties have also been determined [34] (see Scheme 1).…”

Electrochemical Comparative Study of Riboflavin, FMN and FAD Immobilized on the Silica Gel Modified with Zirconium Oxide

“…6 The flavins have in common the isoalloxazine ring system where the redox process occurs, Figure 1b. The nature of the group attached to the N-10, Figure 1a, is the flavin members differentiation and can influence the flavin adsorption orientation on the electrode surface, 7,8 leaving the active site more or less available. The redox process of the flavins is thermodynamically reversible, irrespective of whether one or two electrons per flavin molecule are being transferred, which means that their redox states (quinone state, semiquinone state, hydroquinone state) must be considered.…”

“…10 Another special interest in flavins is the study of their reaction with dihydronicotinamide adenine dinucleotide (NADH). 7,11,12 Many electrochemical investigations have been made with the goal of elucidating the mechanism of this reaction. However a major obstacle found in that kind of study is the relative low difference between the E o´ values of NADH and of free flavin which results in a slow kinetics of this redox reaction.…”