Using data from e + e − annihilation into hadrons, taken with the OPAL detector at LEP at the Z pole between 1991 and 1995, we performed a simultaneous measurement of the colour factors of the underlying gauge group of the strong interaction, C F and C A , and the strong coupling, α s . The measurement was carried out by fitting next-to-leading order perturbative predictions to measured angular correlations of 4-jet events together with multi-jet related variables. Our results, C A = 3.02 ± 0.25(stat.) ± 0.49(syst.) , C F = 1.34 ± 0.13(stat.) ± 0.22(syst.) , α s (M Z ) = 0.120 ± 0.011(stat.) ± 0.020(syst.) , provide a test of perturbative QCD in which the only assumptions are non-abelian gauge symmetry and standard hadronization models. The measurements are in agreement with SU(3) expectations for C F and C A and the world average of α s (M Z ).