Martensitic stainless steels, such as those in the AISI type 4xx series, have good corrosion resistance, good edge retention, high strength, high hardness, and good wear resistance. 1) Maintaining control over the amount of martensite is important when designing alloy compositions and determining heat treatment conditions, because of the contribution of martensite to the mechanical and electrochemical properties in these stainless steels. Dilatometric analysis has been widely used for determining quantitative volume fractions of transformed phases, and many investigations have provided analytical models for converting dilatometric data into volume fractions of the constituent phases. [2][3][4][5][6][7][8] However, most of these previous models have been mainly focused on heat-treatable low-alloy steels whose total amount of alloying element is below 5 wt%. The principle used in these models for dilatometric analysis is based on the relative atomic volume change between parent phase and transformed phase. This volume change is affected by the changes of the crystal structure, the lattice parameters of the unit cells, and the thermal expansion coefficient during phase transformation. The crystal structure of the phase is determined by the thermo-mechanical conditions, while the lattice parameters can vary due to the type and amount of alloying elements added as a consequence of having different atomic radii. [9][10][11][12] The purpose of the present research is to demonstrate an analytical model for predicting the volume fraction of martensite from a dilation curve by considering the effect of alloying elements in Fe-Cr-Ni stainless steel alloys. The dilation curves of Fe-Cr-Ni alloys with different chemical compositions were selected from literature to verify the analytical model, and the effect of alloying elements is discussed as part of this study.