Analysis of sulfonamides, tilmicosin and avermectins residues in typical animal matrices with multi-plug filtration cleanup by liquid chromatography–tandem mass spectrometry detection

Qin, Yuhong; Jatamunua, Freedom; Zhang, Jingru; Li, Yanjie; Yang, Han; Zou, Nan; Shan, Jianguo; Jiang, Yanbin; Pan, Canping

doi:10.1016/j.jchromb.2017.04.006

Cited by 56 publications

(27 citation statements)

References 32 publications

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“…The reported techniques include SPE ; stir bar sorptive extraction based on C 18 coating material , polydimethylsiloxane coating material , and molecularly imprinted polymer (MIP) coating material ; magnetic SPE using a magnetite/silica/poly(methacrylic acid–co‐ethylene glycol dimethacrylate) as sorbent , and a graphene‐based magnetic nanocomposite . Furthermore, novel techniques such as QuEChERS and fabric‐phase sorptive extraction have been successfully applied for the isolation of sulfonamides from milk.…”

Section: Introductionmentioning

confidence: 99%

One‐pot synthesis of a multi‐template molecularly imprinted polymer for the extraction of six sulfonamide residues from milk before high‐performance liquid chromatography with diode array detection

Kechagia

Samanidou

Kabir

et al. 2017

J of Separation Science

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A highly selective molecularly imprinted polymer sorbent was synthesized and employed for the simultaneous determination of six sulfonamide antibiotic residues (sulfanilamide, sulfacetamide, sulfadiazine, sulfathiazole, sulfamerazine, and sulfamethizole) in milk samples. Multi-analyte imprinted particles were used as a sorbent in solid-phase extraction. Sulfonamides were separated on a high-performance liquid chromatography column (Merck-Lichrospher RP18e, 5 μm 250 × 4 mm) and further identified and quantified by diode array detection. Several parameters including required loading of the molecularly imprinted polymer sorbent, mass of milk, volume, and type of elution solvent, as well as time for absorption and elution were investigated to obtain optimal experimental conditions. For comparison purpose, a non-imprinted polymer was applied under the optimum conditions. The validation study according to the European Union Decision 2002/657/EC was based on the investigation of linearity, selectivity, stability, limits of detection and quantitation, decision limit, detection capability, trueness, precision, and ruggedness according to Youden's approach. The decision limit and detection capability values in the milk were achieved from 101.9 to 113.5 μg/kg and from 114.4 to 135.4 μg/kg, respectively, depending on the target sulfonamide drug. Finally, the optimized protocol was successfully applied to commercial milk samples and human breast milk.

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Section: Introductionmentioning

confidence: 99%

One‐pot synthesis of a multi‐template molecularly imprinted polymer for the extraction of six sulfonamide residues from milk before high‐performance liquid chromatography with diode array detection

Kechagia

Samanidou

Kabir

et al. 2017

J of Separation Science

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show abstract

“…Finally, mainly due to mismanagement, among other factors, https://www.wageningenacademic.com/doi/book/10.3920/978-90-8686-863-6 -Sunday, August 22, 2021 8:07:50 PM -IP Address: 44.224.250.200 Pests and vector-borne diseases in the livestock industry 93 4. Ecology-based sustainable strategies to control cattle ticks acaricides leave residues in beef and dairy products as attest recent publications (Macedo et al 2015;Picinin et al 2016;Qin et al 2017), thus threatening consumers' health and food safety, as well as food security. Residues in animal products also create trade barriers (Lively 2013;Schröder et al 2016) that can negatively affect national economies.…”

Section: The Impacts Of Acaricidesmentioning

confidence: 80%

3. Veterinary importance and integrated management of Brachycera flies in dairy farms

Baldacchino¹,

Desquesnes²,

Duvallet³

et al. 2018

Pests and Vector-Borne Diseases in the Livestock Industry

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Worldwide the livestock industry, from small farmers to large industrialized farms, is affected by arthropods and arthropod-borne diseases at various scales, which cause huge losses and are a constraint to socio-economic development. Farmers make considerable efforts to prevent and control pest and disease incidence, often requiring the use of vaccines, if available, drugs and pesticides. Examples of current problems are presented, to set the stage for the detailed and state-of-the-art presentations of specific cases of livestock pests and their associated diseases and modern methods of prevention and control.

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“…Previous study demonstrated that acidic acetonitrile could increase the extraction efficiency and obtain acceptable recoveries for pesticide residues in animal tissues . Moreover, highly nonpolar fats and polar proteins were not significantly dissolved in acetonitrile .…”

Section: Resultsmentioning

confidence: 98%

Dual‐layer column filtration cleanup and gas chromatography‐tandem mass spectrometry detection for the analysis of 39 pesticide residues in porcine meat

Song

Pan

Yang

et al. 2020

J of Separation Science

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A rapid and effective method was developed for the analysis of 39 pesticide residues in porcine meat with dual-layer multiplug filtration cleanup and gas chromatographytandem mass spectrometry detection. The cleanup process was performed with columns packed with two layers, namely multiwalled carbon nanotubes, C18 and anhydrous magnesium sulfate (MgSO 4 ) as top layer, while mixture of florisil and MgSO 4 as bottom layer. A single-layer method was tested in parallel, with columns packed with the same amount of absorbents. Extraction conditions and filtration cleanup process were optimized to obtain satisfied method performance. Method linearity was calculated with coefficients of determination more than 0.995. The limits of quantitation were verified with acceptable accuracy at the lowest spiked concentration of 0.01 mg/kg (except pyrimethanil). The recoveries at three fortified levels (0.01, 0.05, and 0.1 mg/kg) in five replicates were between 74 and 118% (except pyrimethanil) with relative standard deviations range from 1 to 16%. The matrix effects were in the range of 1.01 to 2.84. This new method was applied for the analysis of multipesticide residues in market samples of porcine meat. This study showed the dual-layer multiplug filtration cleanup demonstrated better performance than that with the single-layer columns in cleanup of porcine meat.

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Analysis of sulfonamides, tilmicosin and avermectins residues in typical animal matrices with multi-plug filtration cleanup by liquid chromatography–tandem mass spectrometry detection

Cited by 56 publications

References 32 publications

One‐pot synthesis of a multi‐template molecularly imprinted polymer for the extraction of six sulfonamide residues from milk before high‐performance liquid chromatography with diode array detection

One‐pot synthesis of a multi‐template molecularly imprinted polymer for the extraction of six sulfonamide residues from milk before high‐performance liquid chromatography with diode array detection

3. Veterinary importance and integrated management of Brachycera flies in dairy farms

Dual‐layer column filtration cleanup and gas chromatography‐tandem mass spectrometry detection for the analysis of 39 pesticide residues in porcine meat

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