The phase transformations of PdMn and PdPtMn films were investigated using differential scanning calorimetry ͑DSC͒, x-ray diffraction ͑XRD͒, and transmission electron microscopy ͑TEM͒. The enthalpy for the fcc to L1 0 transformation in the PdMn and PdPtMn thin films has been measured by DSC as −5.4 and −7.6 kJ/ mol at., respectively. The fcc to L1 0 phase transformation was identified by XRD and TEM on as-deposited and annealed samples. The transition temperature for the PdPtMn is approximately 40°C lower than that for PdMn. PdPtMn thin films have better corrosion resistance than PdMn.