Anthocyanins of hybrid hibiscuses

Rakhimkhanov, Z. B.; Sadykov, A. S.; Исмаилов, А. И.; Karimdzhanov, A. K.

doi:10.1007/bf00563333

Chem Nat Compd

1973

DOI: 10.1007/bf00563333

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Anthocyanins of hybrid hibiscuses

Z. B. Rakhimkhanov¹,

A. S. Sadykov²,

А. И. Исмаилов³

et al.

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“…IR spectrum (KBr, ν, cm −1 ): 3300-3400 (OH), 1655 (C=O), 1615-1430 (Ar). UV spectrum (MeOH containing HCl, 0.01%, λ max , nm): 520.Addition of methanolic AlCl 3 (5%) caused a bathochromic shift of 30 nm, which is typical of anthocyans containing free hydroxyls in the 3′-and 4′-positions [4].Acid hydrolysis gave D-glucose, L-rhamnose, and the aglycon with mp >300°C (dec.). UV spectrum (MeOH, 0.01% HCl, λ max , nm): 535; +AlCl 3 , 565.…”

mentioning

confidence: 99%

“…Addition of methanolic AlCl 3 (5%) caused a bathochromic shift of 30 nm, which is typical of anthocyans containing free hydroxyls in the 3′-and 4′-positions [4].…”

mentioning

confidence: 99%

“…Alkaline cleavage of the algycon formed phloroglucinol and protocatechoic acid. Chromatography by PC using n-BuOH:HCl (2 N) (1:1, upper phase) and CH 3 CO 2 H:HCl:H 2 O (5:1:5), R f 0.68 and 0.35, corresponded to cyanidin [4].Stepwise acid hydrolysis of the glycoside by Hcl (4%) in methanol for 25-30 min gave an intermediate and L-rhamnose. The site of attachment of the sugar was determined by oxidative destruction of the glycoside [4,6].…”

mentioning

confidence: 99%

mentioning

confidence: 99%

“…The site of attachment of the sugar was determined by oxidative destruction of the glycoside [4,6]. This formed a biose identical to rutinose [2] that was bonded to C 3 of the aglycon.…”

mentioning

confidence: 99%

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Anthocyan glycoside from Hedera colchica

Alaniya¹,

Kavtaradze²,

Skhirtladze³

2008

Chem Nat Compd

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Hedera colchica is an evergreen vine [1]. Observations carried out by us on separate specimens of H. colchica showed that the color changes depending on the vegetative phase. Thus, the stems and leaves acquire a green color during active vegetation whereas they become reddish during winter. We collected samples of the plant in Tbilisi (Georgia) in January and July 2007 in order to explain the essence of this phenomenon.The flavonol glycoside rutin has been previously isolated from H. colchica [2]. Rutin was not observed in the aqueous alcohol extract of a sample collected in January. It was found that the rutin content varies depending on the season. Rutin accumulated most (0.57%) in summer. In January, its content decreases to only traces whereas the anthocyan content changes in the opposite direction. Anthocyan pigment was completely absent in the summer sample whereas its content in the January sample reached 0.52%.Aerial parts of the plant collected in January were extracted by the method proposed for isolating anthocyan pigments [3]. The extraction was performed using methanol containing conc. HCl (0.1%) at room temperature in the dark. The resulting extract was purified by adsorption chromatography over cellulose sorbent and using reversed-phase HPLC (Agilent HP 1100, Palo Alto, USA) with a UV detector and fixed wavelength of 520 nm. We used an XTerra column (300 × 7.8 mm) packed with Silica gel RP-18 adsorbent (5 μm). The mobile phase flow rate was 2 mL/min. Samples (5 mg) (the fraction containing anthocyan pigment produced by chromatography over cellulose) were dissolved in methanol (100 μL) and injected into the chromatograph. The mobile phase was binary solutions of CH 3 CN and H 2 O containing trifluoroacetic acid (0.1%, from 10:90 to 60:40). The duration was 60 min; retention time of anthocyan, 15.63 min.A pure compound that in daylight on PC gave a pink spot; in UV light, a bright pinkish-red fluorescence; and in ammonia vapor and upon spraying with aqueous NaOH solution (1%), a bright blue color, was produced. IR spectrum (KBr, ν, cm −1 ): 3300-3400 (OH), 1655 (C=O), 1615-1430 (Ar). UV spectrum (MeOH containing HCl, 0.01%, λ max , nm): 520.Addition of methanolic AlCl 3 (5%) caused a bathochromic shift of 30 nm, which is typical of anthocyans containing free hydroxyls in the 3′-and 4′-positions [4].Acid hydrolysis gave D-glucose, L-rhamnose, and the aglycon with mp >300°C (dec.). UV spectrum (MeOH, 0.01% HCl, λ max , nm): 535; +AlCl 3 , 565. This indicated the presence of an o-dihydroxy group in the side chain. Alkaline cleavage of the algycon formed phloroglucinol and protocatechoic acid. Chromatography by PC using n-BuOH:HCl (2 N) (1:1, upper phase) and CH 3 CO 2 H:HCl:H 2 O (5:1:5), R f 0.68 and 0.35, corresponded to cyanidin [4].Stepwise acid hydrolysis of the glycoside by Hcl (4%) in methanol for 25-30 min gave an intermediate and L-rhamnose. The site of attachment of the sugar was determined by oxidative destruction of the glycoside [4,6]. This formed a biose identical to rutinose [2] that was ...

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mentioning

confidence: 99%

“…Addition of methanolic AlCl 3 (5%) caused a bathochromic shift of 30 nm, which is typical of anthocyans containing free hydroxyls in the 3′-and 4′-positions [4].…”

mentioning

confidence: 99%

mentioning

confidence: 99%

mentioning

confidence: 99%

“…The site of attachment of the sugar was determined by oxidative destruction of the glycoside [4,6]. This formed a biose identical to rutinose [2] that was bonded to C 3 of the aglycon.…”

mentioning

confidence: 99%

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Anthocyan glycoside from Hedera colchica

Alaniya¹,

Kavtaradze²,

Skhirtladze³

2008

Chem Nat Compd

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Phenotypic Similarities in Flower Characteristics Between Novel Winter-Hardy Hibiscus Hybrids and Their Tropical Relatives

2019

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Herbaceous winter-hardy Hibiscus spp. in the section Muenchhusia, also known as rosemallows, are attractive ornamental plants found in temperate environments. These should not be confused with woody winter-hardy hibiscus (Hibiscus syriacus L. and related species) which have also been intensively used as ornamental shrubs. During the past 70 years, breeders have attempted to create winter-hardy hibiscus hybrids with novel flower colors resembling the distantly related tropical Chinese hibiscus, Hibiscus rosa-sinensis L. Although direct attempts to hybridize winter-hardy hibiscus with the tropical hibiscus have been unsuccessful, new interspecific herbaceous winter-hardy hibiscus hybrids with a palette of novel flower colors commonly found in tropical hibiscus have been recently introduced. In this review, we outline the historic perspective on interspecific hybridizations in woody and herbaceous winter-hardy hibiscus and discuss breeding approaches to develop herbaceous winter-hardy hibiscus hybrids with novel flower colors and shapes resembling tropical hibiscus cultivars. By creating a broad genetic variability in herbaceous winter-hardy hibiscus hybrids we found a successful approach to increase the range of flower colors and shapes in these species and made them look very like their distant tropical relatives.

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Anthocyanins of hybrid hibiscuses

Cited by 2 publications

References 4 publications

Anthocyan glycoside from Hedera colchica

Anthocyan glycoside from Hedera colchica

Phenotypic Similarities in Flower Characteristics Between Novel Winter-Hardy Hibiscus Hybrids and Their Tropical Relatives

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