“…Similar to the morphology of the Cu coatings, the largest effect on crystal structure (i.e., on the preferred orientation of coating) has the type of electrolyte [5,47]. In both the constant (potentiostatic and galvanostatic) regimes of electrodeposition, the Cu coatings obtained from the basic sulfate electrolyte possessed the (220) preferred orientation, and this preferred orientation did not depend on applied current density or potential, type of cathode used, and concentrations of both Cu(II) ions and sulfuric acid as constituents of the sulfate electrolyte [4,5,48,49]. On the other hand, the mirror bright Cu coatings obtained here used levelling and brightening additives exhibited the strong (200) preferred orientation [5,47].…”