The possible role of the triangle mechanism in the B − decay into D * 0 π − π 0 η and D * 0 π − π + π − is investigated. In this process, the triangle singularity appears from the decay of B − into D * 0 K − K * 0 followed by the decay of K * 0 into π − K + and the fusion of the K + K − , which forms the a 0 (980) or f 0 (980), which finally decay into π 0 η or π + π − , respectively. The triangle mechanism from theK * KK loop generates a peak around 1420 MeV in the invariant mass of π − a 0 or π − f 0 , and it gives sizable branching fractions,