We have investigated the ultrashallow n+/p junction formed by AsH3 plasma doping (PLAD) and the effect of hydrogen on dopant activation. Since hydrogen balance gas (99% H2) was used for AsH3 PLAD, the incorporation of a significant concentration of hydrogen resulted after PLAD. The incorporated hydrogen caused various problems, such as low dopant activation, high resistance, and high leakage current. These problems were traced to hydrogen-induced damage, which was confirmed by cross-sectional transmission electron microscopy (XTEM). Therefore, pre-annealing at low temperature, which can effectively reduce the undesired hydrogen effects, is a necessary step toward obtaining a high-quality, ultrashallow arsenic n+/p junction via AsH3 PLAD.