In the Loess Plateau region, the poor structure and properties of loess slopes will cause many types of geological disasters such as landslides, mudflow, land collapse, soil erosion, and ground cracking. In this paper, an eco-friendly polymer composite fertilizer (PCF) based on corn straw wastes (CS) and geopolymer synthesized from loess was studied. The characterization by FT-IR of the PCF confirmed that graft copolymer is formed, while morphological analysis by scanning electron microscopy and energy dispersive spectroscopy showed that geopolymer and urea were embedded in the polymer porous network. The effects of PCF contents on the compressive strength of loess were investigated. The PCF was characterized in terms of surface curing test, temperature and freeze-thaw aging property, water and wind erosion resistance, and remediation soil acidity and alkalinity property, which indicates that PCF can improve loess slope fixation and stability by physical and chemical effects. Moreover, the loess slope planting experiment showed that PCF can significantly increase the germination rate of vegetation from 31% to 68% and promote the survival rate of slope vegetation from 45.2% to 67.7% to enhance biological protection for loess slopes. The PCF meets the demands of building and roadbed slope protection and water-soil conservation in arid and semi-arid regions, which opens a new application field for multifunctional polymer composite fertilizers with low cost and environmental remediation.