The aim of this paper is to test the convergence hypothesis for the EU countries with Netherlands which is considered as the benchmark. The empirical analysis uses Gross Domestic Product (GDP) per capita in Purchasing Power Parity (PPP) in constant prices of 2005 and covers the period 1950-2010. The empirical approach complementarily employs unit root tests for stochastic convergence and a test proposed by Tomljanovich and Vogelsang (Empirical Econ 27: 49-62, 2002) and Nieswiadomy and Strazicich (Econ Inq 42: 323-340, 2004) that is based on Carlino and Mills' (J Monet Econ 32: 335-346, 1993) methodology. Applying the unit root tests for the relative per capita real GDP series for each country, we are able to reject the unit root hypothesis for 6 out of 14 countries. However, our results suggest there is stronger evidence in favor of convergence when we account for one or two endogenous structural breaks in the intercept and slope of the trend function. Based on Carlino and Mills methodology, we found strong evidence of a catch-up process until the mid-1980 towards the Netherlands for all countries except for the UK, although, after 1985, it is clear that the economies show different behavior which is probably associated with differences in the growth process.