Assessment of pine cone derived activated carbon as an adsorbent in defluoridation

Abstract

A vast population of the world is vulnerable to fluoride contaminated drinking water intake, and there are various defluoridation techniques available to date as well. But the removal of fluoride is still a challenge, especially in remote rural areas because available techniques require proper supervision and equally, ineffective due to economic issues and electricity crisis. Among all methods of defluoridation, adsorption methods are found better to carry out at the community and household level but sometimes demanded a replacement of commercial activated carbon (CAC) due to economic issues and less availability in remote areas. Hence keeping this in mind, the present study assessed the pine cone activated carbon (PCAC) as adsorbent material in the defluoridation that is easy to prepare like any other agriculture-waste material. The activated carbon was prepared using KOH as an impregnating agent for activation of pine cone by pyrolysis technique at 800 °C and has been analyzed for various parameters in the fluoride removal viz. contact time, dose variation, pH and initial fluoride concentration. The maximum adsorption capacity of fluoride on pine cone activated carbon was found 1.34 mg/g of initial fluoride concentration (2-12 mg/L) at pH (6.8-7.0) with a contact period of 45 min. Also, a comparison has been made between Pine Cone Activated Carbon (PCAC) with Commercial Activated Carbon (CAC) based on obtained results. It has been suggested that Pine cone activated carbon is efficient as well as cheap adsorbent and can be used for the removal of fluoride from drinking water in rural areas.

A comprehensive analysis and optimization of coal-biomass mixed fuel for sustainable power generation

“…Conversely, charcoal stands out with the lowest ash content at 1.96%. Pine cone (0.81%) and pine needle (4.13%) also have very low ash content whereas coal has the highest ash content of 60.31% [19,20]. HHV varies across the fuels, with charcoal (Pinewood Charcoal) exhibiting the highest value at 7327 MJ/kg, followed by pine needle (4300 MJ/kg), pine cone (4200 MJ/kg), and coal (2597 MJ/kg).…”

KOH-modified bamboo charcoal loaded with α-FeOOH for efficient adsorption of copper and fluoride ions from aqueous solution

“…Wang et al 29 synthesized alkali-modified biochar from bamboo impregnation with KOH via pyrolysis and used it for Cu 2+ removal with higher adsorption capacity than the original bamboo charcoal. Thakur et al 30 used pine biomass mixed with KOH by high-temperature pyrolysis to synthesize alkali-modified pine biochar, achieving better adsorption for F − . Depositing metal compounds on biochar surfaces can increase the binding sites and enhance adsorption capacity.…”