Asymmetric 1,3,4-oxadiazole derivatives containing naphthalene and stilbene units: Synthesis, optical and electrochemical properties

Lu, Huixiong; He, Daohang

doi:10.1016/j.saa.2013.12.104

Cited by 12 publications

(5 citation statements)

References 43 publications

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“…Notably, the 1 H NMR spectra of target compounds show two fine doublets as well as a coupling constant (16.7−16.0 Hz) corresponding to the olefinic protons (CHCH) from trans-stilbene, which are further confirmed by the FTIR spectra. 30 All spectral and analytical data are consistent with the assigned structures.…”

Section: ■ Results and Discussionsupporting

confidence: 73%

Synthesis, Biological Evaluation, and Structure–Activity Relationship Study of Novel Stilbene Derivatives as Potential Fungicidal Agents

Jian

Liu

et al. 2015

J. Agric. Food Chem.

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A total of 22 novel stilbene derivatives containing the 1,3,4-oxadiazole moiety and trimethoxybenzene were designed and synthesized. Their chemical structures were characterized by (1)H and (13)C nuclear magnetic resonance, infrared, and high-resolution mass spectrometry. Bioassay results revealed that some of the title compounds showed potent in vivo fungicidal activities against three phytopathogenic fungi (Pseudoperonospora cubensis, Colletotrichum lagenarium, and Septoria cucurbitacearum) from cucurbits at 600 μg/mL. Notably, compounds 4b, 4d, 4i, 4k, and 4l exhibited a broad spectrum and remarkably high activities against those fungi, some of which even showed a comparable control efficacy to that of the commercial fungicides. Three-dimensional quantitative structure-activity relationship based on comparative molecular field analysis with good predictive ability (q(2) = 0.516; r(2) = 0.920) was reasonably discussed. For the first time, the present work suggested that the stilbene derivatives containing the 1,3,4-oxadiazole moiety could be developed as potential fungicides for crop protection.

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Section: ■ Results and Discussionsupporting

confidence: 73%

Synthesis, Biological Evaluation, and Structure–Activity Relationship Study of Novel Stilbene Derivatives as Potential Fungicidal Agents

Jian

Liu

et al. 2015

J. Agric. Food Chem.

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“…Scanning at positive potential values the compounds 3a-h demonstrated irreversible oxidation processes (Fig. 2) [58,59]. Compounds 3b and 3g exhibited different oxidation behavior than that of the other compounds due to the presence of the amino group.…”

Section: Electrochemical Behaviormentioning

confidence: 96%

Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage

et al. 2020

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Elsevier has created a COVID-19 resource centre with free information in English and Mandarin on the novel coronavirus COVID-19. The COVID-19 resource centre is hosted on Elsevier Connect, the company's public news and information website. Elsevier hereby grants permission to make all its COVID-19-related research that is available on the COVID-19 resource centre-including this research content-immediately available in PubMed Central and other publicly funded repositories, such as the WHO COVID database with rights for unrestricted research re-use and analyses in any form or by any means with acknowledgement of the original source. These permissions are granted for free by Elsevier for as long as the COVID-19 resource centre remains active.

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“…In recent years, focus has shift to the compounds of isoxazoles and oxadiazoles which have practical uses in many civilian and military applications [22][23][24][25][26][27][28][29]. Various bis-isoxazoles and bis-oxazoles have been synthesized which show potential for melt-castable applications, including the compound of 3,3'-bis-oxadiazole-5,5'-bis-methylene dinitrate (BODN, Figure 1) [30].…”

Section: Introductionmentioning

confidence: 99%

Thermal Kinetic Performance and Thermal Safety of 3,3’‐Bis‐Oxadiazole‐5,5’‐Bis‐Methylene Dinitrate

Li¹,

Luo²,

Wang³

et al. 2020

Propellants Explo Pyrotec

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DSC and TG/DTG were performed to investigate the thermal kinetic performance and thermal safety of 3,3'bis-oxadiazole-5,5'-bis-methylene dinitrate (BODN) under a non-isothermal condition. The results reveal that the thermal behavior of BODN can be divided into three stages including a melting endothermic process and two decomposition exothermic processes. The apparent activation energy (E) and pre-exponent parameters (A) of the first exothermic decomposition reaction are 147.45 kJ mol À 1 and 10 13.77 s À 1 , and its kinetic equation was obtained from the DSC curves. The self-accelerating decomposition temperatures (T SADT), thermal ignition temperatures (T TIT), and critical temperatures of the thermal explosion (T b) to evaluate its thermal stability and safety are 166.41°C, 178.09°C, and 204.47°C, respectively. The positive values of free energy of activation (ΔG ¼ 6 = 135.49 kJ mol À 1) indicate that the decomposition process of BODN must proceed under the heating condition.

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Asymmetric 1,3,4-oxadiazole derivatives containing naphthalene and stilbene units: Synthesis, optical and electrochemical properties

Cited by 12 publications

References 43 publications

Synthesis, Biological Evaluation, and Structure–Activity Relationship Study of Novel Stilbene Derivatives as Potential Fungicidal Agents

Synthesis, Biological Evaluation, and Structure–Activity Relationship Study of Novel Stilbene Derivatives as Potential Fungicidal Agents

Selenylated-oxadiazoles as promising DNA intercalators: Synthesis, electronic structure, DNA interaction and cleavage

Thermal Kinetic Performance and Thermal Safety of 3,3’‐Bis‐Oxadiazole‐5,5’‐Bis‐Methylene Dinitrate

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