Asymmetric induction by the radical copolymerization of styrene with maleic anhydride in l‐menthol

Fujihara, Hisashi; Yamazaki, Kunihiro; Yoshihara, Masakuni; Maeshima, Toshihisa

doi:10.1002/pol.1979.130170806

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1980

1984

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Cited by 19 publications

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“…It was thought that a protic chiral solvent might influence the geometry of the free radical addition complex. In t h s point of view, we found earlier that optically active copolymer was obtained by the radical copolymerization of styrene with maleic anhydride in Q-menthol (6). Thus, with a hope to find the additional example of asymmetric induction in a free radical addition, the reaction of cyclohexanone with 2-octene was carried out in P-menthol using benzoyl peroxide as the radical initiator, and indeed an asymmetric induction was found to occur.…”

Section: Introductionmentioning

confidence: 93%