Biocatalytically synthesized of water-soluble alkoxysulfonate-functionalized poly(3,4-ethylenedioxythiophene)

Zhou, Heyuan; Zhao, Yun; Shen, Xiaofeng; Ni, Zhong‐Hai

doi:10.1016/j.matchemphys.2018.01.022

Cited by 5 publications

(6 citation statements)

References 30 publications

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“…In addition, a new absorption band appeared in the visible light range of 400−750 nm under strong alkaline conditions during the dedoping process by using NaOH (Figure 1c). 27,43 It was assumed that this visible absorption band was attributed to the HOMO−LUMO transition within the undoped PEDOT-S chain. 19 The distribution of insoluble PEDOT:PSS within the hydrogel matrix can be affected by the polydisperse particle size and lead to a reduced conductivity.…”

Section: Results and Disscussionmentioning

confidence: 99%

“…Due to the hydrophobic PEDOT core being enveloped by excess hydrophilic PSS shells and resulting in a highly dispersed particle distribution and aggregation, the conductivity of PEDOT:PSS composite conductive hydrogel is poor. To address this, organic solvents like ethylene glycol or dimethyl sulfoxide are added to weaken the electrostatic interaction between PEDOT and PSS, strip the insulating agent PSS, and induce microphase separation, allowing more conductive PEDOT to participate in charge carrier transport and thereby enhancing conductivity. ,− Several studies have shown that polymer solubility and stability can be improved by incorporating hydrophilic side chains, such as phosphoric esters, sulfonate esters, or carboxylate groups . Notably, Chevrot et al documented the utilization of FeCl 3 as a catalyst in the polymerization of sulfonated PEDOT (PEDOT-S), but its purifying process was quite challenged due to the combination of sulfonic acid and iron ions .…”

Section: Introductionmentioning

confidence: 99%

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Sensitive Wearable Strain Sensor Based on a Self-Doped Conductive Hydrogel

Ji,

He,

Sun

et al. 2024

ACS Appl. Electron. Mater.

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Conductive hydrogels have been widely applied to develop flexible and wearable sensors. Classic conductive polymers such as poly (3,4ethylenedioxythiophene):poly(styrenesulfonate) exhibit high conductivity and biocompatibility, but their intrinsic insolubility may affect the establishment of conductive pathways, thereby further impeding the enhancement of both electrical and mechanical properties. In this study, a self-doped highly conductive poly(3,4-ethylenedioxythiophene) sulfonate (PEDOT-S) solution was obtained by photopolymerization, avoiding the introduction of iron ions. Following this, we developed a double network (DN) hydrogel system from poly(vinyl alcohol) and polyacrylamide via a freezing−thawing approach, combining with PEDOT-S as conductive agent. The hydrogel exhibited robust mechanical strength, adhesive capability, and remarkable conductive sensitivity. As a strain sensor, the conductive hydrogel can be used to detect body motion and vocal cord vibrations, providing promising potential for application in flexible and wearable devices.

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Section: Results and Disscussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Sensitive Wearable Strain Sensor Based on a Self-Doped Conductive Hydrogel

Ji,

He,

Sun

et al. 2024

ACS Appl. Electron. Mater.

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“…[91] For instance, peroxidases have been used for the oxidative polymerization of poly(3,4-ethylenedioxythiophene)sulfonate (PEDOT-S) and poly(3,4-ethylenedioxythiophene) (PEDOT). [92,93]…”

Section: Biocatalysismentioning

confidence: 99%

Biosourced Monomers: Toward Sustainable Conjugated Polymers for Organic Electronics

Boivin

Dupont

Gendron

et al. 2022

Macro Chemistry & Physics

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Organic electronic materials are starting to appear in various applications, but there are still hurdles to overcome before the average consumer can get them in their hands. Right now, most polymers in the field of organic electronics are made from petroleum derivatives. However, new sources of platform chemicals and monomers are being explored. This perspective article highlights ways that have been explored to avoid the use of petrochemicals and demonstrates new pathways that can be taken to increase the sustainability of conjugated polymers in organic electronics.

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“…Horseradish peroxidase was used for polymerization of a water soluble derivative of EDOT without a template. 33 The laccase from the fungus Trametes hirsuta was applied to EDOT polymerization on the so templates (PAMPS, PSS, DNA). [34][35][36] As was mentioned above, CNTs are a promising material for SC electrodes.…”

Section: Introductionmentioning

confidence: 99%