Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II)

Abstract

In the title compound, [Pd(C17H13N2O)2], the PdII atom is tetra­coordinated by two N atoms and two O atoms from two bidentate methylphenyl­diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the PdII atom are trans to each other (as the PdII atom lies on a crystallographic inversion centre) with O—Pd—N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the PdII atom and the coordinated O and N atoms are 1.966 (3) and 2.009 (3) Å, respectively.

Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato}palladium(II)

“…The distances between the Pd II atom and O and N are 1.9717 (9), 1.9727 (9), 2.0194 (10) and 2.0209 (10) Å, respectively. These bond distances and angles are similar to those found in the crystal structure of bis[4-methyl-2-(2H-benzotriazol-2-yl)phenolato]palladium (II) (Tsai et al, 2009;Lin et al, 2010). The dihedral angle between the two fluoro-substituted benzene (C9-C14)/(C24-C29) rings is 39.03 (6)°.…”

“…For applications of palladium(II)-Schiff base complexes, see: Ali et al (2002); Gupta & Sutar (2008). For related structures, see: Jiang et al (2008); Tsai et al (2009); Mohd Tajuddin et al (2010); Lin et al (2010). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986).…”

Bis{1-[(E)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)

“…The metals in metal-complex dno's are predominantly chromium and copper, and to a lesser extent cobalt, iron, and nickel. The ligand (E)-1-(o-tolyldiazenyl)naphthalen-2-ol, has been used previously to form complexes with Cu(OAc) 2 .H 2 O (Tai et al, 2010) and Pd(OAc) 2 (Lin et al, 2010). Herein, we report of the crystal structure of a new copper complex of a similar ligand.…”

“…For general background to azo compounds and their use in dyes, pigments and advanced materials, see: Lee et al (2004); Oueslati et al (2004). For related structures, see: Tai et al (2010); Lin et al (2010).…”

Crystal structure of bis{1-[(E)-(2-methoxyphenyl)diazenyl]naphthalen-2-olato-κ3O,N2,O′}copper(II) containing an unknown solvate

“…For applications of azo compounds, see: Millington et al (2007); Hallas & Choi (1999); Ho et al (1995); Sharma et al (2008). For related structures, see: Tai et al (2010); Lin et al (2010…”