Drawing upon the functional characteristics of blockchain technology, this paper envisages the feasibility and reliability of developing a charity donation service system loaded onto blockchain in response to the complex service demands encountered by charity operators due to the Covid-19 epidemic. With blockchain technology's support as the underlying data book, this paper focuses on the practical issues of charity donation fund and material allocation, as well as information release and sharing, charity donation organization, and organization self-management. The paper thereby discusses the key technologies in terms of overall structure design, specific service sector, and functional design of the donation service system and further summarizes the operational mechanism of the system as combined with the needs of help-seeking, receiving, and management users. It is argued that all the above proposals have the potential to alleviate the trust crisis of charity services in China in view of low transparency. The paper expects to provide a useful reference for charity business innovation propelled by blockchain technology. INDEX TERMS blockchain technology, the Covid-19 outbreak, charity donation, service system, reliability.