Ca5Cl3(C2)(CBC): eine Verbindung mit Schichtstruktur und einer ungewöhnlichen Anionenkombination

Reactions of the zinc(I) complex [Zn 2 (Mesnacnac) 2 ] (Mesnacnac = [(2,4,6-Me 3 C 6 H 2 )NC(Me)] 2 CH) with solid K 3 Bi 2 dissolved in liquid ammonia yield crystals of the compound K 4 [ZnBi 2 ]·(NH 3 ) 12 (1), which contains the molecular, linear heteroatomic [Bi À Zn À Bi] 4À polyanion (1 a). This anion represents the first example of a three-atomic molecular ion of metal atoms being iso(valence)-electronic to CO 2 and being synthesized in solution. The analogy of the discrete [BiÀ ZnÀBi] 4À anion and the polymeric 1 1 [(ZnBi 4/2 ) 4À ] unit to monomeric CO 2 and polymeric SiS 2 is rationalized.

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BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

Benda

Köchner

Schäper

et al. 2014

Angewandte Chemie

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BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

et al. 2014

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Reactions of the zinc(I) complex [Zn2(Mesnacnac)2] (Mesnacnac = [(2,4,6-Me3C6H2)NC(Me)]2CH) with solid K3Bi2 dissolved in liquid ammonia yield crystals of the compound K4[ZnBi2]⋅(NH3)12 (1), which contains the molecular, linear heteroatomic [Bi-Zn-Bi](4-) polyanion (1 a). This anion represents the first example of a three-atomic molecular ion of metal atoms being iso(valence)-electronic to CO2 and being synthesized in solution. The analogy of the discrete [Bi-Zn-Bi](4-) anion and the polymeric ∞(1)[(ZnBi4/2)(4-)] unit to monomeric CO2 and polymeric SiS2 is rationalized.

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Festkörperchemie 1999

Köhler

Wiemhöfer

2000

Nachr Chem

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Elementstrukturen, neue Synthesewege und Verbindungen, weiterentwickelte Charakterisierungsmethoden, Arbeiten zu Struktur‐Eigenschafts–Beziehungen und neuen Funktionsmaterialien sind Eckpunkte festkörperchemischer Forschung des letzten Jahres. Das Interesse an der gezielten Strukturierung im nano– und mesoskopischen Bereich nimmt zu, was unter anderem zu einigen neuen Hybrid– und Kompositmaterialien führte.

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Ca5Cl3(C2)(CBC): eine Verbindung mit Schichtstruktur und einer ungewöhnlichen Anionenkombination

Cited by 6 publications

References 26 publications

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

Festkörperchemie 1999

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Ca5Cl3(C2)(CBC): eine Verbindung mit Schichtstruktur und einer ungewöhnlichen Anionenkombination

Cited by 6 publications

References 26 publications

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]4−, a Linear Polyanion that is Iso(valence)‐electronic to CO2

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]4−, a Linear Polyanion that is Iso(valence)‐electronic to CO2

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]4−, a Linear Polyanion that is Iso(valence)‐electronic to CO2

Festkörperchemie 1999

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BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂

BiZn Bond Formation in Liquid Ammonia Solution: [BiZnBi]⁴⁻, a Linear Polyanion that is Iso(valence)‐electronic to CO₂