Capillary ion electrophoresis screening of nerve agent degradation products in environmental samples using conductivity detection

In situ determination of nerve agents in various matrices by portable capillary electropherograph with contactless conductivity detection

“…Contact conductivity detection with CE for the detection of NA degradation products was first demonstrated by Rosso and Bossle [41] and later by Nassar et al [33,34]. Due to the obvious advantages of the recently developed contactless conductivity detection (C4D) approach [42,43], contact conductivity detection has been replaced by C4D in CE.…”

Poly(dimethylsiloxane) Microchip Electrophoresis with Contactless Conductivity Detection for Measurement of Chemical Warfare Agent Degradation Products

“…Although conventional gas chromatography, (Riches et al 2005;Pardasani et al 2006) liquid chromatography, (Liu et al 2004;D'Agostino et al 2006) capillary electrophoresis, (Nassar et al 1998(Nassar et al , 1999Rosso and Bossle 1998;Lagarrigue et al 2006) and ion chromatography (Vermillion and Crenshaw 1997;Piao et al 2005) offer high sensitivity and exquisite selectivity, they may not be suitable for use as rapid screening methods nor are they typically used for field applications because of their size and technical complexity. Due to their sensitivity, analysis speed, and portability, an intense interest has emerged in the Y.…”

A Review of CE Detection Methodologies

“…% Triton X-100. 75 An improvement in the detection limits to 10 -7 to 10 -8 M can be achieved by replacing standard conductivity detection with suppression conductivity detection for the analysis of anions. [76][77][78] In suppression conductivity, the buffer counterion is replaced by ionic exchange or electrodialysis producing a weakly dissociated acid (anion analysis) or base (cation analysis).…”