2015
DOI: 10.1039/c4ta07040b
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Cation ordering in A-site-deficient Li-ion conducting perovskites La(1−x)/3LixNbO3

Abstract: Cation-deficient perovskites exhibit complex local atomic arrangements which cannot be adequately described by average crystal structure models. By combining reciprocal-space electron diffraction analysis and direct observations of atom positions using state-of-the-art scanning transmission electron microscopy, we clarify the nature of the cation ordering within A-site-deficient perovskite single crystals of La (1Àx)/3 Li x NbO 3 (x ¼ 0 and x ¼ 0.04). Both materials are found to have complex modulated crystal … Show more

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Cited by 41 publications
(38 citation statements)
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“…This is corroborated by the fact that sulfur-containing molecules (such as thiophene) are effective passivating agents for perovskite solar cells where the Lewis acid-base interactions are available. [191][192][193] A number of nonhalide-based perovskite structures and antiperovskites have been employed for lithium-ion battery materials, such as CoTiO 3 , [194] BaSnO 3 , [195] NaNbO 3 , [196] KZnF 3 , [197] Na 0.85 Ni 0.45 Co 0.55 F 3.56 , [198] Li 3/8 Sr 7/16 Ta 3/4 Hf 1/4 O 3 , [199] Li 3/8 Sr 7/16 -Hf 1/4 Ta 3/4 O 3 , [200] Ag 1+ 3 Mo 6+ (O 3 F 3 ), [201] La 0.56−y Li 0.33 TiO 3−3y F 3y , [202] Li 3/8 Sr 7/16 Hf 1/4 Ta 3/4 O 3 , [203] KCo 0.54 Mn 0.46 F 3 , [204] La (1−x)/3 Li x NbO 3 , [205] and Li 0.33 La 0.557 TiO 3 . [206] Apart from the electrode materials in lithium-ion batteries, [207,208] these perovskite derivatives are also common for the lithium-ion battery electrolytes [209,210] and the lithium-sulfur batteries.…”
Section: (12 Of 20)mentioning
confidence: 99%
“…This is corroborated by the fact that sulfur-containing molecules (such as thiophene) are effective passivating agents for perovskite solar cells where the Lewis acid-base interactions are available. [191][192][193] A number of nonhalide-based perovskite structures and antiperovskites have been employed for lithium-ion battery materials, such as CoTiO 3 , [194] BaSnO 3 , [195] NaNbO 3 , [196] KZnF 3 , [197] Na 0.85 Ni 0.45 Co 0.55 F 3.56 , [198] Li 3/8 Sr 7/16 Ta 3/4 Hf 1/4 O 3 , [199] Li 3/8 Sr 7/16 -Hf 1/4 Ta 3/4 O 3 , [200] Ag 1+ 3 Mo 6+ (O 3 F 3 ), [201] La 0.56−y Li 0.33 TiO 3−3y F 3y , [202] Li 3/8 Sr 7/16 Hf 1/4 Ta 3/4 O 3 , [203] KCo 0.54 Mn 0.46 F 3 , [204] La (1−x)/3 Li x NbO 3 , [205] and Li 0.33 La 0.557 TiO 3 . [206] Apart from the electrode materials in lithium-ion batteries, [207,208] these perovskite derivatives are also common for the lithium-ion battery electrolytes [209,210] and the lithium-sulfur batteries.…”
Section: (12 Of 20)mentioning
confidence: 99%
“…Line splitting increases again at y = 0.3, which is presumably due to interference from impurity-phase diffraction peaks. The crystal lattice undergoes a small amount of orthorhombic distortion as Li + gradually replaces La 3+ ; the symmetry of the structure changes from the original orthorhombic ((Li 0.01 La 0.33 ) 1–2 x Sr x NbO 3 ) to tetragonal ((Li 0.1 La 0.3 ) 1–2 x Sr x NbO 3 ) and finally transforms into pseudo-cubic ((Li 0.25 La 0.25 ) 1–2 x Sr x NbO 3 ) …”
Section: Resultsmentioning
confidence: 87%
“…This means 1/3 of the vertex La sites are inherent vacancies which accommodate Li ions. Hence, this special Li-containing plane is named as the A 1 layer [23,24] with rich vacancy networks, and the middle-plane gap between neighbouring A 1 layers is called the A 2 layer, which contains only O atoms (purple in Figure 1a). In the charging or discharging process of the Li ion battery, these layers could be the Li + -conductive channels for ionic transport in the solid electrolyte.…”
Section: Resultsmentioning
confidence: 99%
“…Among the available lithium-ion-conducting solid electrolytes, ceramic oxides (10 −5~1 0 −3 S•cm −1 ) such as perovskite materials Li 3x La 2/1−x TiO 3 (LLTO) [18][19][20][21] and Li x La (1−x)/3 NbO 3 (LLNO) [22][23][24], anti-perovskite Li 3 OX (X = Cl, Br) [25][26][27] and garnet structured Li 7 La 3 Zr 2 O 12 (LLZO) [28][29][30][31] have received much attention due to their good electrochemical stability and considerable potential to push the limit of ionic conductivity towards a desired level (~10 −2 S•cm −1 ) in the industrial application of batteries. Their ionic conductivity follows such a microscopic ion migration mechanism: low occupancy of the Li + on the vacancy sites; low migration energy barrier for ion hopping; and network-like available sites (vacancies) [32] to interconnect the migration pathways of the mobile ions in these solid electrolytes [1].…”
Section: Introductionmentioning
confidence: 99%