“…[ 1 , 2 , 3 ] Compared with ceramic counterparts, polymer dielectrics possess inherent advantages of high voltage endurance, scalability, low cost, and high breakdown strength. [ 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 ] However, they suffer from low operating temperatures and thus fall short of the demands for electrical energy storage and conversion in harsh environments. [ 13 , 14 ] For example, biaxially oriented polypropylene (BOPP), the state‐of‐the‐art commercially available polymer dielectric used in the power inverter, can only reliably operate at temperatures below 105 °C, while the engine compartment temperature in electric vehicles can exceed 120 °C.…”