This study reports a gallium-based thermal interface material (GBTIM) consisting of gallium oxides dispersed uniformly into the 99 % gallium metal. The wettability of GBTIM with other materials is disclosed and compared. The thermal conductivity of GBTIM measured by a computer-controlled Mathis TCi thermal analyzer is ∼13.07 W m −1 K −1 at room temperature, which is significantly higher than that of conventional thermal greases. An experimental facility is described to measure the thermal resistance across the GBTIM under steady-state conditions and the thermal interface resistance is measured as low as 2.6 mm 2 kW −1 with a pressure of 0.05 MPa, which is an order lower than that of the best commercialized thermal greases. Further, the GBTIM is formed into a desired shape to enhance thermal transfer, such as semi-liquid paste or thermal pad, which can be cut into a required shape.