Thin film Al 2 O 3 /Al-rich Al 2 O 3 /SiO 2 structures were fabricated on p-Si substrates.Radio-frequency magnetron co-sputtering was used to form Al-rich Al 2 O 3 thin film as the charge-trapping layer of nonvolatile Al 2 O 3 memory. Capacitance-voltage measurements showed a large hysteresis due to charge trapping in the Al-rich Al 2 O 3 layer. The charge trap density was estimated to be 42.7 × 10 18 cm -3 , which is the largest value ever reported for an Al-rich Al 2 O 3 layer; it is six times larger than that of a conventional metal-nitride-oxide-silicon memory. Thermal annealing was found to reduce the leakage current of the Al 2 O 3 blocking layer, thereby providing this structure with better data retention at room temperature than an as-deposited one. In addition, the annealed structure was found to exhibit good data retention even at 100°C.