China is experiencing serious acid rain contamination, with Beijing among the worst-hit areas. To understand the chemical feature and the origin of inorganic ions in precipitation of Beijing, 128 precipitation samples were collected and analyzed for major water-soluble ions and δ 34 S. The pH values ranged from 3.68 to 7.81 and showed a volume weighted average value (VWA) of 5.02, with a frequency of acid rain of 26.8 %. The VWA value of electrical conductivity (EC) was 68.6 μS/cm, which was nearly 4 times higher than the background value of northern China. Ca 2+ represented the main cation; SO 4 2− and NO 3 − were the dominant anion in precipitation. Our study showed that SO 4 2− and NO 3 − originated from coal and fossil fuel combustion; Ca 2+ , Mg 2+ , and K + were from the continental sources. The δ 34 S value of SO 4 2− in precipitation ranged from +2.1 to +12.8‰ with an average value of +4.7‰. The δ 34 S value showed a winter maximum and a summer minimum tendency, which was mainly associated with temperature-dependent isotope equilibrium fractionation as well as combustion of coal with relatively positive δ 34 S values in winter. Moreover, the δ 34 S values revealed that atmospheric sulfur in Beijing are mainly correlated to coal burning and traffic emission; coal combustion constituted a significant fraction of the SO 4 2− in winter precipitation.