Chemischer Informationsdienst
 1973
DOI: 10.1002/chin.197341161
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ChemInform Abstract: STABILE CARBENOIDE 51. MITT. ZUR UMLAGERUNG VON LI‐ALKOXIDEN AUS DICHLORMETHYLLITHIUM UND CARBONYLVERBINDUNGEN IN ALPHA‐CHLOROXIRANE UND ALPHA‐CHLORALDEHYDE

Gert Koebrich1,
Jutta Grosser2,
Wolfgang Werner3

Abstract: Die Addition von Dichlormethyl‐Li (II) z.B. an die Carbonylverbindungen (I)‐ führt zu den Li‐Alkoxiden (III), deren Protolyse die Alkohole (IV) und deren Silylierung die Silyläther (V) ergibt.

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