Chiral Pesticides with Asymmetric Sulfur: Extraction, Separation, and Determination in Different Environmental Matrices

López-Cabeza, Rocío; Francioso, Antonio

doi:10.3390/separations9020029

Cited by 12 publications

(6 citation statements)

References 57 publications

(139 reference statements)

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“…For instance, it has typically been found that the biodegradation of organic compounds by fungi, including pesticides, is a comparatively longer process and occasionally does not result in the entire elimination of contaminants [15]. The fact that different fungal strains have been found to only partially degrade pesticides is another disadvantage of fungal biodegradation [82]. It has occasionally been discovered that these secondary metabolites are significantly more toxic than the original chemicals [83].…”

Section: Fungi and Their Enzymesmentioning

confidence: 99%

Pesticides in Foods: Towards Bioremediation Biocatalysts?

Perpetuini,

Nzobouh Fossi,

Kwak

et al. 2023

Catalysts

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The presence of hazardous chemical compounds in foods is a growing concern in almost every country. Although some toxins come from microbial contamination, a major part comes from residues of pesticides used for plant health and food preservation. Despite plans to decrease their use, the concentration of hazardous residues encountered in food is growing. The societal solution to this issue is to find alternatives to chemicals and replace the most hazardous by biodegradable, fewer toxic compounds. However, as this greener transition takes some time, any transitory solution to decrease the risks of contamination is welcome. Among them, the stimulation of microbial pesticide degradation in food in a similar way to bioremediation in the environment would be very positive. In this review, we present the problem of food contamination, focusing on organophosphates and organochlorines, and the various possibilities of microbial decontamination. We discuss the possible use of microbial biocatalysts as a biopreservation tool. We conclude that, although this process is very promising, it lacks research taking into account the various degradation products and the elaboration of screening procedures able to choose some rare, efficient biopreservation strains.

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Section: Fungi and Their Enzymesmentioning

confidence: 99%

Pesticides in Foods: Towards Bioremediation Biocatalysts?

Perpetuini,

Nzobouh Fossi,

Kwak

et al. 2023

Catalysts

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show abstract

“…The design of SFC-MS interfaces has been improved over the years and, with the advancement of column technology, namely the availability of sub-2 μm particle size ultra-highperformance columns, the SFC-MS technology proved to be a good tool for both separation and sample preparation [12][13][14]. There are examples of employing SFC-MS for the analysis of pesticides, plant materials, pharmaceuticals, or metabolomic studies [15][16][17][18][19][20][21].…”

Section: Introductionmentioning

confidence: 99%

Analysis of doping control samples using supercritical fluid chromatography‐tandem mass spectrometry: Ready for routine use

Wuest

Gavrilović

Cowan

et al. 2023

J of Separation Science

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Supercritical fluid chromatography is proving to be a good separation and sample preparation tool for various analytical applications and, as such, has gained the attention of the anti‐doping community. Here, the applicability of supercritical fluid chromatography hyphenated to tandem mass spectrometry for routine doping control analysis was tested. A multi‐analyte method was developed to cover 197 drugs and metabolites that are prohibited in sport. More than 1000 samples were analyzed by applying a “dilute and inject” approach after hydrolysis of glucuronide metabolites. Additionally, a comparison with routinely used liquid chromatography‐mass spectrometry was performed with 250 of the 1000 samples and a number of past positive anti‐doping samples. It revealed some features where supercritical fluid chromatography‐tandem mass spectrometry was found to be complementary or advantageous to liquid chromatography‐mass spectrometry for anti‐doping purposes, such as better retention of analytes that are poorly retained in reversed‐phase liquid chromatography. Our results suggest that supercritical fluid chromatography‐tandem mass spectrometry is sensitive (limit of detection <50% relevant minimum required performance level required by the World Anti‐Doping Agency for anti‐doping analysis), reproducible, robust, precise (analytes of interest area coefficient of variation <5%; retention time difference coefficient of variation <1%) and complementary to existing techniques currently used for routine analysis in the World Anti‐Doping Agency accredited laboratories.

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“…The offline preconcentration method in CE is also known as the sample pretreatment method. At present, various sample preparation methods were used before CE analysis, mainly including ultrasound-assisted extraction (UAE) [15], microwave-assisted extraction [16], refluxing extraction [17], supercritical fluid extraction [18], and so forth. However, most of the methods tended to require large consumption of organic solvents, as well as difficulties in reaching satisfactory extraction efficiency [19].…”

Section: Introductionmentioning

confidence: 99%

Miniaturized matrix solid‐phase dispersion and solid‐phase clear‐up combined with capillary electrophoresis for efficient determination of trace bioactive components in complicated sample matrix: Take Wubi Shanyao Pill as an example

Wei

Yaxin

Zang

et al. 2023

J of Separation Science

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Accurate quantitative analysis of trace analytes in a complicated matrix is a challenge in modern analytical chemistry. An appropriate analytical method is considered to be one of the most common gaps during the whole process. In this study, a green and efficient strategy based on miniaturized matrix solid-phase dispersion and solid-phase extraction combined with capillary electrophoresis was first proposed for extracting, purifying and determining target analytes from complicated matrix, using Wubi Shanyao Pill as an example. In detail, 60 mg of samples were dispersed on MCM-48 to obtain high yields of analytes, then the extract was purified with a solid-phase extraction cartridge. Finally, four analytes in the purified sample solution were determined by capillary electrophoresis. The parameters affecting the extraction efficiency of matrix solid-phase dispersion, purification efficiency of solid-phase extraction and separation effect of capillary electrophoresis were investigated. Under the optimized conditions, all analytes demonstrated satisfactory linearity (R 2 >0.9983). What's more, the superior green potential of the developed method for the determination of complex samples was confirmed by the Analytical GREEnness Metric Approach. The established method was successfully applied in the accurate determination of target analytes in Wubi Shanyao Pill and thus provided reliable, sensitive, and efficient strategy support for its quality control.

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Chiral Pesticides with Asymmetric Sulfur: Extraction, Separation, and Determination in Different Environmental Matrices

Cited by 12 publications

References 57 publications

Pesticides in Foods: Towards Bioremediation Biocatalysts?

Pesticides in Foods: Towards Bioremediation Biocatalysts?

Analysis of doping control samples using supercritical fluid chromatography‐tandem mass spectrometry: Ready for routine use

Miniaturized matrix solid‐phase dispersion and solid‐phase clear‐up combined with capillary electrophoresis for efficient determination of trace bioactive components in complicated sample matrix: Take Wubi Shanyao Pill as an example

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